Selected methods for the synthesis of sulfoxides and sulfones with emphasis on oxidative protocols

S. Matavos-Aramyan, Sadaf Soukhakian, M. Jazebizadeh
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引用次数: 29

Abstract

Abstract A large variety of organosulfur compounds has been shown to exhibit diverse biological effects such as anti-oxidant effects, anti-inflammatory properties, inhibition of platelet aggregation, reduction of systolic blood pressure, and reduction of cholesterol. In addition, these sulfoxides and sulfones show wide and significant applications as commodity chemicals in various fields of chemistry. Thus, the synthesis of sulfoxides and sulfones has remained a point of attraction for synthetic organic chemists. Selected from an array of methods used to synthesize the sulfoxides or sulfones, oxidation of sulfides is the most promising one. This review summarizes chemoselective methods for the synthesis of the sulfoxides and sulfones with focus on the oxidative protocols, which will help researchers to explore and utilize the mentioned protocols for different organic transformations. Graphical Abstract
选择合成亚砜和砜的方法,重点介绍氧化方法
大量的有机硫化合物已被证明具有不同的生物效应,如抗氧化作用、抗炎作用、抑制血小板聚集、降低收缩压和降低胆固醇。此外,这些亚砜和砜作为商品化学品在化学的各个领域显示出广泛而重要的应用。因此,亚砜和砜的合成一直是有机合成化学家关注的焦点。从一系列合成亚砜或砜的方法中,硫化物氧化法是最有前途的一种方法。本文综述了亚砜和砜类化合物的化学选择性合成方法,重点介绍了氧化方法,这将有助于研究人员探索和利用这些方法进行不同的有机转化。图形抽象
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