Processing of open-pore silicon foams using graphite composite as space holder

Abstract

In this study, a novel space holder is used for the fabrication of Si foams. The space holder is a graphite composite (GC) with regular spheroidal cells. Conventional space holder materials are not suitable for casting Si foams. The main issue in this context is the differences between the melting point of the foam's base material and the one of common space holders. GC offers many advantages as e.g. low cost, good dissolution by oxidation, high melting point and non-toxicity. This type of space holder is chemically stable when being in contact with liquid and solid Si, and it is, hence, suitable for a melt metallurgical processing route. Si foams are manufactured by applying replication casting. The resulting foam geometry and its surface are analyzed using LM and SEM. XRD measurements are performed to investigate the quality of the Si foam in terms of contamination by graphite or oxygen.