The Template Synthesis, Characterization, and Thermal Investigation of New Heterocyclic Binucleating Schiff Base Complexes

Abstract

Abstract 1‐Amino‐5‐benzoyl‐4‐phenyl‐1H‐pyrimidine‐2‐one (L′H2) reacts with benzil (L″O2) and salts Cu(AcO)2 · H2O, NiCl2 · 6H2O, Co(AcO)2 · 4H2O, CdCl2 · 2H2O in 2:1:2 molar ratio in n‐butanol to give several solid complexes of the general composition [(M)2(L′)2(L″)(X)4] · nH2O. The precursor and the metal complexes of the Schiff base have been characterized by elemental analyses, molar conductances, IR spectra, electronic, and thermal studies.