Ruthenium(III) Catalysis in Perborate Oxidation of 5-Oxoacids

S. Devi, P. Krishnamoorthy, B. Muthukumaran
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引用次数: 1

Abstract

Ruthenium(III) catalyzes perborate oxidation of substituted 5-oxoacids in acidic solution. The catalyzed oxidation is first order with respect to the oxidant and catalyst. The rate of ruthenium(III) catalyzed oxidation displays the Michaelis-Menten kinetics on the reductant and is independent of [H
钌(III)在5-氧酸过硼酸盐氧化中的催化作用
钌(III)在酸性溶液中催化取代5-氧酸的过硼酸氧化。对于氧化剂和催化剂来说,催化氧化是一级的。钌(III)催化氧化的速率在还原剂上表现出Michaelis-Menten动力学,与[H]无关
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