A Taguchi Optimization Study about The Dissolution of Colemanite in Ammonium Bisulfate (NH4HSO4) Solution

IF 1 4区工程技术 Q4 CHEMISTRY, MULTIDISCIPLINARY

Iranian Journal of Chemistry & Chemical Engineering-international English Edition Pub Date : 2021-09-26 DOI:10.30492/IJCCE.2021.530973.4757

Havva Mumcu Şimşek, R. Guliyev

{"title":"A Taguchi Optimization Study about The Dissolution of Colemanite in Ammonium Bisulfate (NH4HSO4) Solution","authors":"Havva Mumcu Şimşek, R. Guliyev","doi":"10.30492/IJCCE.2021.530973.4757","DOIUrl":null,"url":null,"abstract":"In this study, the optimum conditions of the dissolution of colemanite (2CaO.3B2O3.5H2O) ore in ammonium bisulfate (NH4HSO4) solution were examined by using Taguchi fractional design methods, and an alternative reactant for boric acid extraction process from colemanite ore was specified. The studied parameters and optimum conditions for the dissolution process were in the following; reaction temperature: 50˚C, solid/liquid ratio: 0.1 g/mL, particle size: -80 mesh, mixing speed: 600 rpm and reaction time: 25 minutes. Particle size, mixing speed and reaction time had the most significant effect on dissolution, when compared to the others. Accordingly, the dissolution efficiency of colemanite was found to be 99.54% under optimum conditions, and using NH4HSO4 as a solvent enabled the selective separation of boron from the colemanite ore. The ammonium sulphate formed as a by-product was converted into NH4HSO4 by the addition of appropriate stoichiometric amount of sulfuric acid and fed back into the dissolution vessel.","PeriodicalId":14572,"journal":{"name":"Iranian Journal of Chemistry & Chemical Engineering-international English Edition","volume":"45 1","pages":""},"PeriodicalIF":1.0000,"publicationDate":"2021-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Iranian Journal of Chemistry & Chemical Engineering-international English Edition","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.30492/IJCCE.2021.530973.4757","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

Abstract

In this study, the optimum conditions of the dissolution of colemanite (2CaO.3B2O3.5H2O) ore in ammonium bisulfate (NH4HSO4) solution were examined by using Taguchi fractional design methods, and an alternative reactant for boric acid extraction process from colemanite ore was specified. The studied parameters and optimum conditions for the dissolution process were in the following; reaction temperature: 50˚C, solid/liquid ratio: 0.1 g/mL, particle size: -80 mesh, mixing speed: 600 rpm and reaction time: 25 minutes. Particle size, mixing speed and reaction time had the most significant effect on dissolution, when compared to the others. Accordingly, the dissolution efficiency of colemanite was found to be 99.54% under optimum conditions, and using NH4HSO4 as a solvent enabled the selective separation of boron from the colemanite ore. The ammonium sulphate formed as a by-product was converted into NH4HSO4 by the addition of appropriate stoichiometric amount of sulfuric acid and fed back into the dissolution vessel.

查看原文本刊更多论文

煤柱石在硫酸氢铵(NH4HSO4)溶液中溶解的田口优化研究

本研究采用田口分级设计法，考察了柱石矿(2CaO.3B2O3.5H2O)在硫酸铵(NH4HSO4)溶液中溶解的最佳条件，并确定了柱石矿硼酸萃取工艺的备选反应物。研究的溶出工艺参数和最佳条件为:反应温度:50℃，料液比:0.1 g/mL，粒度:-80目，搅拌速度:600转/分，反应时间:25分钟。与其他因素相比，粒径、搅拌速度和反应时间对溶解的影响最为显著。结果表明，在最佳溶出条件下，柱石的溶出效率为99.54%，且以NH4HSO4为溶剂，可实现柱石矿石中硼的选择性分离，副产物硫酸铵通过加入适量的硫酸转化为NH4HSO4，并反馈到溶出容器中。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Iranian Journal of Chemistry & Chemical Engineering-international English Edition CHEMISTRY, MULTIDISCIPLINARY-ENGINEERING, CHEMICAL

CiteScore

2.80

自引率

22.20%

发文量

审稿时长

6-12 weeks

期刊介绍： The aim of the Iranian Journal of Chemistry and Chemical Engineering is to foster the growth of educational, scientific and Industrial Research activities among chemists and chemical engineers and to provide a medium for mutual communication and relations between Iranian academia and the industry on the one hand, and the world the scientific community on the other.