Condensation route from 1,1,1-tris(diethylboryl)propane to pentaethyl-1,5-dicarba-closo-pentaborane(5)via arachno-CB4(10) and nido-C2B4(8) carbaboranes

R. Köster, R. Boese, B. Wrackmeyer, H. Schanz
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引用次数: 14

Abstract

Diethyl(prop-1-ynyl)borane 1 reacts, in the presence of a large excess of tetraethyldiborane(6), to give the new substituted 1-carba-arachno-pentaborane(10)4 as the first intermediate which can be isolated; 4 rearranges via the nido-C2B4(8) carbaboranes A and Bto the known pentaethyl-1,5-dicarba-closo-pentaborane(5)5which is characterized by single crystal X-ray analysis.
1,1,1-三(二乙基)丙烷经arachno-CB4(10)和nido-C2B4(8)碳硼烷缩合成戊乙基-1,5-二碳-近戊硼烷(5)的缩合路线
二乙基(丙-1-炔基)硼烷1在大量过量的四乙基二硼烷(6)存在下反应生成新取代的1-碳- aracho -五硼烷(10)4作为可分离的第一中间体;4通过nido-C2B4(8)碳硼烷A和b重排为已知的五乙基-1,5-二碳-近五硼烷(5)5,通过单晶x射线分析表征。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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