Organic Chemistry of Polyanilines: Tailoring Properties to Technological Applications

M. C. Miras, D. Acevedo, N. Monge, E. Frontera, C. Rivarola, C. Barbero
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引用次数: 16

Abstract

The use of organic chemistry reactions to introduce additional functional groups on polyanilines is described. Among the reactions discussed are: electrophilic aromatic substitution, nucleophilic addition to the aromatic rings, nu- cleophilic substitution on the amine groups and reactions on pendant groups. The use of combinatorial chemistry tech- niques, by coupling of combinatorially synthesised diazonium salts with polyaniline, to produce a functionalized polyani- lines library is also reviewed. The modification of polyaniline introduces or alters different properties of the materials: solubility, self-doping and redox coupled ion exchange. The tailoring of those properties to technical applications is there- fore examined.
聚苯胺的有机化学:裁剪性质与技术应用
介绍了利用有机化学反应在聚苯胺上引入附加官能团的方法。讨论的反应有:亲电芳取代反应、亲核芳环加成反应、亲氨取代反应和悬垂基反应。本文还综述了利用组合化学技术,通过组合合成重氮盐与聚苯胺的偶联,来产生一个功能化的聚苯胺谱库。聚苯胺的改性引入或改变了材料的不同性质:溶解度、自掺杂和氧化还原偶联离子交换。因此,研究了如何使这些特性适应技术应用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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