The effect of bentonite loading on the curing, tensile and morphological properties of Ethylene-Propylene-Diene Monomer (EPDM) composites

M. Mathialagan, H. Ismail
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Abstract

Curing behaviour, tensile and morphological properties of bentonite (Bt) filled Ethylene-Propylene-Diene Monomer (EPDM) composites at various Bt loading were investigated. EPDM/Bt composites were prepared using a laboratory size two-roll mill by adding 0 to 70 part per hundred rubber (phr) of Bt. Curing time (t90) and scorch time (tS2) were reduced initially with 0 to 30 phr Bt loading and increased subsequently at 50 and 70 phr. Results obtained showed that tensile strength and elongation at break of EPDM/Bt composites were increased with incorporation of 0 to 50 phr Bt and decreased at 70 phr Bt loading, whereas the tensile modulus at 100% elongation (M100) showed an increasing trend with increasing Bt loading from 0 to 70 phr. Scanning Electron Microscope (SEM) was used to examine the morphology of tensile fractured surface which revealed the good interaction between Bt particles and EPDM to an optimum Bt loading of 50 phr and agglomeration of Bt particles at 70 phr.
膨润土负载对EPDM复合材料固化、拉伸及形态性能的影响
研究了膨润土(Bt)填充三元乙丙橡胶(EPDM)复合材料在不同Bt负载下的固化性能、拉伸性能和形态性能。在实验室尺寸的双辊轧机上,加入0 ~ 70份/百橡胶(phr)的Bt制备EPDM/Bt复合材料。在0 ~ 30份/百橡胶(phr)的Bt负荷下,固化时间(t90)和焦化时间(tS2)最初减少,随后在50和70份/百橡胶(phr)的Bt负荷下增加。结果表明:当掺入0 ~ 50 phr Bt时,EPDM/Bt复合材料的抗拉强度和断裂伸长率均有所提高,而当掺入70 phr Bt时,拉伸模量(M100)随掺入量的增加呈上升趋势;利用扫描电镜(SEM)观察拉伸断裂表面形貌,发现Bt颗粒与三元乙丙橡胶相互作用良好,最佳Bt载荷为50 phr, 70 phr时Bt颗粒团聚。
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