A recyclable epoxy for composite wind turbine blades

IF 1.8 Q3 ENGINEERING, MANUFACTURING
Ming-Sung Wu, B. Jin, Xin Li, S. Nutt
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引用次数: 19

Abstract

Abstract Disposal of wind turbine blades, which are generally non-biodegradable and non-recyclable products comprised largely of fiber-reinforced thermoset polymers (FRPs), pose environmental problems when components reach end-of-service-life. Because the global wind turbine market shows steady year-over-year growth, the need for a recycling solution for wind blade FRPs is urgent and growing rapidly. In the present study, recyclable resins, formulated using proprietary epoxy curing agents (Cleavamine®, Adesso), were charactered and analyzed for processability and recyclability. Protocols for vacuum infusion processing were developed for these recyclable resins. Secondly, laminates of glass fibers and the above epoxy matrices were first produced then recycled, and the properties of recovered fibers were evaluated. Matrix and laminate properties were compared to a benchmark commercial epoxy presently used in commercial wind blades. Results showed that vacuum infusion with the recyclable resins yielded laminates with low void contents and properties comparable to non-recyclable commercial epoxies, and the recovered glass fibers retained surface quality comparable to virgin fibers. Furthermore, results also showed that the recovered matrix residue can be re-used in second-life applications, effectively completing the closed-loop recycling method in this study. Graphical Abstract
用于复合风力涡轮机叶片的可回收环氧树脂
风力涡轮机叶片通常是不可生物降解和不可回收的产品,主要由纤维增强热固性聚合物(frp)组成,当部件达到使用寿命时,其处置会带来环境问题。由于全球风力涡轮机市场呈现出逐年稳定增长的趋势,因此对风力叶片frp回收解决方案的需求迫在眉睫,而且增长迅速。在本研究中,使用专有的环氧固化剂(clecleamine®,Adesso)配制的可回收树脂,对其加工性和可回收性进行了表征和分析。对这些可回收树脂制定了真空灌注处理方案。其次,先将玻璃纤维和上述环氧基复合制成层合板,然后进行回收,并对回收纤维的性能进行评价。将基体和层压板性能与目前用于商用风力叶片的基准商用环氧树脂进行了比较。结果表明,用可回收树脂真空灌注得到的层压板的孔隙率低,性能与不可回收的环氧树脂相当,回收的玻璃纤维保持了与原始纤维相当的表面质量。此外,研究结果还表明,回收的基质残渣可以二次利用,有效地完成了本研究的闭环回收方法。图形抽象
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来源期刊
CiteScore
4.00
自引率
0.00%
发文量
11
审稿时长
16 weeks
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