Excess Properties and Theoretical Evaluation on Ternary Systems of 1-Pentanol in n-Hexane Solution with some Organic Compounds at 313 K Using Ultrasonic Technique

Abstract

: The parameters like density( ρ ), ultrasonic velocity (U), and viscosity ( η ) were experimentally measured. The excess parameters like adiabatic compressibility, acoustic impedance, free volume, free length, internal pressure and ultrasonic velocity in addition to K value were computed from the experimental data. The variation of these parameters at a constant temperature for the three ternary systems, namely OMP + 1-pentanol+n-hexane, N, N-DMF + 1-pentanol+n-hexane, and MMP + 1-pentanol+n-hexane, have been discussed in the light of molecular interaction. Further, certain theoretical studies are validated with respect to experimental velocities, and the Chi-square test for the goodness of fit is also applied to check the validity of such theoretical models.