Interpolyelectrolyte Complex Chitosan – Alginate for Soil Structuring

B.Kh. Мussabayeva, Zh. S. Kassymova, L. Orazzhanova, A. Klivenko, A. Sabitova, B.B. Bayahmetova
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Abstract

The interpolyelectrolyte complex of the composition [chitosan]:[alginate] = [1]:[4] was prepared by mixing a hydrochloric acid solution of cationic polyelectrolyte chitosan and an aqueous solution of anionic polyelectro-lyte sodium alginate. The complex of chitosan and sodium alginate biopolymers was first used as a soil struc-turizer. Due to low humus and light mechanical composition, the dark chestnut soil of the dry-steppe zone of the East Kazakhstan region is subjected to erosion. Introducing a polymer complex into the specified soil con-tributed to the improvement of wind resistance, an increase in humidity, and a decrease in water permeability. The soil surface treated with a complex of biopolymers showed pronounced resistance to the action of planar and trickle water erosion due to aggregation of particles with a diameter of < 0.01 mm. The fraction of soil particles obtained by mechanical destruction of structured aggregates with a diameter of 3-1 mm has a well-expressed ability to self-aggregate during the humidification - drying process. The results of the vegetation and field experience in tillage with an interpolyelectrolyte complex showed a positive effect of the complex on the growth and development of radish of the Rubin variety and, as a result, an increase in radish yield by 2 times was achieved. The obtained results indicate the effectiveness of the structuring action of the chitosan-alginate complex for poorly structured soils.
壳聚糖-海藻酸盐复合聚电解质在土壤结构中的应用
以阳离子聚电解质壳聚糖的盐酸溶液与阴离子聚电解质海藻酸钠的水溶液混合,制备了[壳聚糖]:[海藻酸钠]=[1]:[4]的聚电解质间复合物。壳聚糖-海藻酸钠生物聚合物复合物首次被用作土壤结构化剂。由于腐殖质低,机械成分轻,东哈萨克斯坦地区干草原地带的黑栗色土壤易受侵蚀。在特定土壤中引入聚合物复合物有助于提高抗风能力,增加湿度,降低透水性。经生物聚合物复合物处理的土壤表面由于聚集了直径< 0.01 mm的颗粒而对平面和细流侵蚀表现出明显的抵抗作用。通过机械破坏直径为3-1 mm的结构性团聚体获得的土壤颗粒的比例在加湿干燥过程中具有良好的自团聚能力。植被试验和田间试验结果表明,复合电解质对红豆品种萝卜的生长发育有积极的促进作用,可使红豆产量提高2倍。所得结果表明壳聚糖-海藻酸盐复合物对结构不良的土壤的结构作用是有效的。
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