Interprétation de la double structure observée dans l'onde de détonation du nitrométhane gazeux

Abstract

Calculations of the reaction zone of the detonation of gaseous nitromethane, either pure or diluted with oxygen, in the range of equivalence ratio Φ between 0.1 and 1.75, show that for 1.75⩾Φ⩾1.3 the chemical energy is released in two main successive reaction steps characterized by very different induction times. These results corroborate the experimental observations of two levels of cellular structures in the same range of equivalence ratios. To our knowledge this work is the first which deals with the problem of nonmonotonous chemical energy release behind the leading shock of a detonation wave.