Synthesis of the Bi 2O 3@BiOI@UiO-66 Composites and Their Enhanced Photocatalytic Activity Under Visible Light

Jijun Tang, Tang Zhang, Zhengzhou Duan, Chuwen Li, Chunfeng Meng, Yamei Zhang, Qiyuan Zhang, Dongmei Hou, Qinyun Xv, Yu Zhu
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Abstract

Bi2O3 is a kind of photocatalyst with excellent performance, which can generate photo-generated electrons under light. Through the recombination of Bi2O3 and BiOI, photogenerated electrons are more easily generated. UiO-66 is added to form a ternary composite material, which improves the stability of the material. Through simulated visible light degradation experiments, it was found that the ternary composite material had a significant degradation effect on rhodamine and tetracycline, which was 22.2 times and 1.04 times the original. This is mainly due to the addition of BiOI to widen the photo sensing interval of Bi2O3 and reduce the forbidden band width of Bi2O3. After loading this composite material on UiO-66, it has a coating effect on the material, which hinders the secondary combination of photogenerated electrons and holes, and improves the photocatalytic efficiency. Bi2O3@BiOI@UiO-66 composite material has high efficiency and stability, and is an excellent photocatalytic degradation material.
Bi 2O 3@BiOI@UiO-66复合材料的合成及其在可见光下的增强光催化活性
Bi2O3是一种性能优异的光催化剂,在光照下可以产生光生电子。通过Bi2O3与BiOI的复合,更容易产生光生电子。加入UiO-66形成三元复合材料,提高了材料的稳定性。通过模拟可见光降解实验,发现三元复合材料对罗丹明和四环素的降解效果显著,分别是原材料的22.2倍和1.04倍。这主要是由于bii的加入扩大了Bi2O3的光敏间隔,减小了Bi2O3的禁带宽度。将该复合材料加载到UiO-66上后,对材料产生涂层效应,阻碍了光生电子与空穴的二次结合,提高了光催化效率。Bi2O3@BiOI@UiO-66复合材料效率高、稳定性好,是一种优异的光催化降解材料。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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