ChemInform Abstract: Synthesis of Diverse Benzotriazoles from Aryne Precursors Bearing an Azido Group via Inter- and Intramolecular Cycloadditions.

ChemInform Pub Date : 2016-12-06 DOI:10.1002/chin.201652267
Suguru Yoshida, Takamoto Morita, Takamitsu Hosoya
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Abstract

Starting from 3-(azidoalkoxy)aryne precursor, a diverse range of bis-1,2,3-triazoles (IV) are obtained via a sequential azide-alkyne and azide-aryne cycloaddition, while unique ring-fused benzotriazoles (VI) are obtained via an intramolecular azido-aryne cycloaddition.

摘要/ Abstract摘要:含叠氮基团的芳香前体通过分子间和分子内环加成合成多种苯并三唑。
从3-(叠氮烷氧基)芳烷前体开始,通过叠氮烷-炔和叠氮烷-芳烷的连续环加成得到了各种各样的双-1,2,3-三唑(IV),而通过分子内叠氮烷-芳烷的环加成得到了独特的环融合苯并三唑(VI)。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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