Application of Non Ionic Surfactant – Alkylpolyglucoside as Chemical Flooding

A. P. Gustianthy, Y. Krisnandi, Usman Usman
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引用次数: 2

Abstract

Alkylpolyglucosides (APG) is an environment-friendly surfactant prepared from renewable raw materials namely glucose and fatty alcohol in catalysis system of p-Toluenesulfonic acid. This surfactant is nonionic surfactant which has not effect on hard water and pH changes, thus makes it potential to be used as a chemical flooding surfactant. APG was prepared by using fatty alcohol varying in chain length from 1-dodecanol (C12) and 1-tetradecanol (C14). This paper discusses the effect of alkyl chain length of APG as hydrofobic side to their physical properties such as interfacial tension, and capability as chemical flooding surfactant for oil recovery in capillary pressure test. As results, it is shown that at the same concentration, APG with 1-tetradecanol (APG-C14) as a chain length has lower interfacial tension than APG-C12, having critical micelle concentration of 3 %. Both surfactant then were tested for Jirak field oil recovery in capillary presure test. It reveals that the increase of alkyl chain length of APG causes an increase in oil recovery (%), 13.797 % of APG-C14 and 10.733% of APG-C12. To conclude, APG with long alkyl chain length potentially become chemical flooding surfactant for oil recovery.
非离子表面活性剂烷基聚葡萄糖苷在化学驱中的应用
烷基多糖苷(APG)是以可再生原料葡萄糖和脂肪醇为原料,在对甲苯磺酸催化体系中制备的一种环保型表面活性剂。该表面活性剂为非离子表面活性剂,对硬水和pH值变化无影响,具有作为化学驱用表面活性剂的潜力。以1-十二醇(C12)和1-十四醇(C14)等不同链长的脂肪醇为原料制备了APG。探讨了烷基链长度作为疏水侧对APG界面张力等物性的影响,以及在毛细管压力试验中作为化学驱表面活性剂采油性能的影响。结果表明,在相同浓度下,以1-十四醇(APG- c14)为链长的APG的界面张力低于APG- c12,临界胶束浓度为3%。然后对这两种表面活性剂进行了毛细压力试验,对Jirak油田的采收率进行了测试。结果表明,随着烷基链长度的增加,APG- c14和APG- c12的原油采收率分别提高了13.797%和10.733%。综上所述,烷基链长较长的APG具有成为化学驱采油表面活性剂的潜力。
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