The Novel Polymorphic Form of Bis(3,5,7-triaza-1-azoniatricyclo[]decane) bis(-oxo)-tris(-oxo)-nonakis(-oxo)-nonaaqua-decaoxo-hepta-molybdenum-di-zinc(II) dihydrate, Synthesis, and Properties
R. Kruszyński, Tomasz Sierański, Bartłomiej Lewiński, A. Trzesowska-Kruszynska, Ewelina Czubacka
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引用次数: 0
Abstract
The reaction of molybdophosphoric acid with zinc carbonate followed by addition of hmta leads to formation of a triclinic polymorph of bis(3,5,7-triaza-1-azoniatricyclo[]decane) bis(-oxo)-tris(-oxo)-nonakis(-oxo)-nonaaqua-decaoxo-hepta-molybdenum-di-zinc(II) dihydrate in a one pot simple reaction. The obtained compound has been characterised by IR, UV-Vis spectroscopy, elemental analysis, and X-ray crystallography. A detailed comparison between both polymorphic forms: triclinic A, A, A, , , , and A3 and monoclinic A, A, A, , , , and A3 was performed. The influence of the synthesis procedure on polymorph formation was described.
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