Microstructure and properties of high emissivity coatings

Zhigang Dan , Daqiang Cang , Huimin Zhou , Hao Bai , Yanbin Zong
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引用次数: 13

Abstract

A new coating on lining in industrial furnace for energy saving has been developed. Properties and microstructure of the coatings were revealed by emissivity instrument, X-ray diffraction (XRD), transmission electron microscope (TEM) and scanning electron microscope (SEM), respectively. The result indicates that the emissivity of coatings is higher than 0.90 and the thickness of coatings is about 200 μm. ZrO2, Cr2O3 and SiC in the coating benefit practical applications of coatings at high temperature with durable high emissivity and the continuous structure between the coatings and the substrate makes the coatings high cohesion and excellent adhesion for both specimens with and without sintering at high temperature. Result from laboratory experiment shows that the heating speed of specimen with coating is higher than that of controlled specimen and the temperature increases 30°C during the heating. The average temperature drop of specimen with coatings has a 13.5% improvement in the cooling speed. The application of coatings on the checker brick in a blast furnace of 1750 m3 indicates that the coating causes the blast temperature to an average increase of 28°C, reduces the fluctuation of blast temperature before the blowing-in and leads to a fuel saving of 10% approximately.

高发射率涂层的组织与性能
研制了一种新型工业炉衬节能涂料。利用发射率仪、x射线衍射仪(XRD)、透射电镜(TEM)和扫描电镜(SEM)对涂层的性能和微观结构进行了表征。结果表明,涂层的发射率大于0.90,涂层厚度约为200 μm。涂层中的ZrO2、Cr2O3和SiC具有持久的高发射率,有利于涂层在高温下的实际应用,涂层与基体之间的连续结构使得涂层在高温烧结和不高温烧结时都具有高的凝聚力和良好的附着力。室内实验结果表明,涂层试样的加热速度比对照试样快,加热过程中温度升高30℃。涂层后试样的平均降温速度提高了13.5%。在1750 m3高炉上涂布的结果表明,涂布使高炉温度平均提高28℃,减少了高炉进气前的温度波动,节油约10%。
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