A Divergent Synthesis of Uncommon Sugars from Furanaldehyde

IF 1.7 4区化学 Q3 CHEMISTRY, ORGANIC

Synlett Pub Date : 2005-05-12 DOI:10.1055/S-2005-869846

Lizhi Zhu, A. Talukdar, Guisheng Zhang, J. P. Kedenburg, Peng Wang

引用次数: 7

Abstract

A practical synthetic strategy has been developed for producing uncommon sugars. This method employed kinetic enzymatic resolution of 1-(2-furyl)ethanol, and followed by NBS-mediated Achmatowicz rearrangement to constructα,β-unsaturated lactones. After further derivatization, five representative uncommon sugar units were successfully synthesized.

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从呋喃醛中分离合成稀有糖

已经开发出一种实用的合成策略来生产不常见的糖。该方法采用动态酶解1-(2-呋喃基)乙醇，然后通过nbs介导的Achmatowicz重排构建α，β-不饱和内酯。经进一步衍生，成功合成了五个具有代表性的不常见糖单元。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Synlett 化学-有机化学

CiteScore

3.40

自引率

5.00%

发文量

369

审稿时长

1 months

期刊介绍： SYNLETT is an international journal reporting research results and current trends in chemical synthesis in short personalized reviews and preliminary communications. It covers all fields of scientific endeavor that involve organic synthesis, including catalysis, organometallic, medicinal, biological, and photochemistry, but also related disciplines and offers the possibility to publish scientific primary data.