Surface Free Energy for the Evaluation of Asphalt Binder Stripping

S. Sarsam, Esraa Thamer Al – Azawee
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Abstract

Stripping is one of the major distresses within asphalt concrete pavements caused due to penetration of water within the interface of asphalt-aggregate matrix. In this work, one grade of asphalt cement (40-50) was mixed with variable percentages of three types of additives (fly ash, fumed silica, and phosphogypsum) to obtained an modified asphalt cement to resist the effect of stripping phenomena .The specimens have been tested for physical properties according to AASHTO. The surface free energy has been measured by using two methods namely, the wilhelmy technique and the Sessile drop method according to NCHRP-104 procedures. Samples of asphalt concrete using different asphalt cement and modified asphalt cement percentages(4.1,4.6 and 5.6) were prepared and tested for stripping phenomena by using Marshall Immersion method (The index of retained stability test(I.R.S) ≥75 %. When using Sessile drop method the value of surface free energy of asphalt cement grade (40-50) was about 8.8 ergs/cm2, while when using Wilhelmy technique the value of surface free energy of asphalt cement was 30.71 ergs/cm2. Finally, a mathematical relationship was obtained by using (SPSS) Software between the strippingasphalt concrete using conditioned and unconditioned specimens data (I.R.S) %, the contact angle, the total surface free energy for asphalt cement and modified asphalt cement with fume silica.
评价沥青粘结剂剥离的表面自由能
剥落是沥青混凝土路面的主要病害之一,是由于水渗入沥青-骨料基质界面而引起的。在这项工作中,将一个等级的沥青水泥(40-50)与三种不同百分比的添加剂(粉煤灰、气相二氧化硅和磷石膏)混合,得到一种改性沥青水泥,以抵抗剥离现象的影响。根据NCHRP-104程序,用wilhelmy法和Sessile滴法两种方法测量了表面自由能。配制不同沥青水泥和改性沥青水泥掺量(4.1、4.6和5.6)的沥青混凝土试样,采用马歇尔浸渍法(irs≥75%)检测剥离现象。采用Sessile drop法时,40-50级沥青水泥的表面自由能约为8.8 ergs/cm2,而采用Wilhelmy法时,沥青水泥的表面自由能为30.71 ergs/cm2。最后,利用SPSS软件得到了条件和非条件试样数据(i.r.s.) %与沥青水泥和掺硅灰改性沥青水泥的接触角、总表面自由能之间的数学关系。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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16 weeks
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