Process water inhibition method for hydraulic testing

Renata S. Krymskaya, An Gritskevich, R. Khodzhaev
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Abstract

Since any hydro-testing is closely related to storage of the tested metal products, the first stage of any hydro-testing is to clean the inner surface of the metal product from either preservative or corrosion products that appeared during storage. Nowadays, we widely use polymers and polymer-based materials for cleaning metals and alloys surfaces of corrosion products. Such agents must satisfy the following requirements: firstly, firmly bind pollution and oxidized forms of metals, preventing surface passivation; secondly, be easily removed from the surface after cleaning; thirdly, components of the cleaning composition should not cause surface oxidation. However, these cleaning methods may not be suitable for hydro-testing due to possible formation of highly toxic waste water, so we often use methods of simultaneous washing with safer soda and citric acid under high pressure, followed by purging with dry air. The paper studies aqueous solutions of N-M-1 corrosion inhibitor mixed with alkali as a corrosion suppressing method in hydraulic tests before commissioning of any product pipelines in order to reduce concentration of a toxic inhibitor in inhibited water. The experiment had two focuses: to assess effectiveness of a new mixture in terms of corrosion inhibition during product pipelines commissioning and to assess toxicity of the mixture using an acid test on two testing objects from two different systematic groups. We proved that, without losing its corrosion inhibition effectiveness in hydro-testing, the mixture can be safely dumped in sewer systems, being preliminarily acidified to acceptable pH values, thanks to lowered N-M-1 concentration. Apart from that, we identified a synergistic effect of N-M-1 corrosion inhibitor acting with NaOH alkali.
水力试验用工艺水抑制法
由于任何水试都与被试金属制品的储存密切相关,因此任何水试的第一阶段是清洁金属制品的内表面,清除储存期间出现的防腐剂或腐蚀产物。目前,我们广泛使用聚合物和聚合物基材料来清洁金属和合金的腐蚀产品表面。这类试剂必须满足以下要求:首先,牢固地结合污染和氧化形式的金属,防止表面钝化;其次,清洗后易于从表面去除;第三,清洗组合物的成分不应引起表面氧化。但是这些清洗方法由于可能会形成剧毒的废水,可能不适合进行水试,所以我们经常采用在高压下用比较安全的苏打和柠檬酸同时清洗,然后用干燥空气清洗的方法。本文研究了N-M-1缓蚀剂水溶液与碱的混合作为任何产品管道调试前的水力抑制腐蚀方法,以降低抑制水中有毒缓蚀剂的浓度。该实验有两个重点:在产品管道调试期间评估新混合物在缓蚀方面的有效性,以及通过对来自两个不同系统组的两个测试对象进行酸试验来评估混合物的毒性。我们证明,由于N-M-1浓度降低,在不失去其缓蚀效果的情况下,混合物可以安全地倾倒在下水道系统中,并初步酸化至可接受的pH值。除此之外,我们还发现了N-M-1缓蚀剂与NaOH碱的协同作用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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