K. Hansongnern, Luksamee Sahavisit, C. Pakawatchai
{"title":"Crystal Structure of cis-Bis(5-chloro-2-(phenylazo)pyridine)-dichlororuthenium(II)","authors":"K. Hansongnern, Luksamee Sahavisit, C. Pakawatchai","doi":"10.2116/ANALSCIX.24.X57","DOIUrl":null,"url":null,"abstract":"The complex [Ru(Clazpy)2Cl2] (Clazpy = 5-chloro-2-(phenylazo)pyridine) was synthesized and characterized by X-ray diffraction analysis. The geometry around ruthenium(II) was distorted octahedral with coordinating from two chloro ligands and four N-donor atoms of two Clazpy units. The chloros are cis while the N(pyridine) atoms are trans. The Ru-N(pyridine) distance (2.037(2)A) is slightly short compared to those in other ruthenium(II) complexes with azoimine ligands.","PeriodicalId":7796,"journal":{"name":"Analytical Sciences: X-ray Structure Analysis Online","volume":"5 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2008-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"3","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Analytical Sciences: X-ray Structure Analysis Online","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2116/ANALSCIX.24.X57","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 3
Abstract
The complex [Ru(Clazpy)2Cl2] (Clazpy = 5-chloro-2-(phenylazo)pyridine) was synthesized and characterized by X-ray diffraction analysis. The geometry around ruthenium(II) was distorted octahedral with coordinating from two chloro ligands and four N-donor atoms of two Clazpy units. The chloros are cis while the N(pyridine) atoms are trans. The Ru-N(pyridine) distance (2.037(2)A) is slightly short compared to those in other ruthenium(II) complexes with azoimine ligands.