Development of Suspension-Based Plasma and HVOF Spray TiO2 Coatings

Abstract

Thermal spray is a versatile process that produces high-quality coatings possessing diverse properties such as superhydrophobicity, wear resistance, corrosion resistance, dielectric properties etc. Conventionally, powder feedstock is used in thermal spray, and this process is commercialised in numerous industrial processes. However, liquid feedstock based thermal spray is still in its development phases, due to limited information available on process parameters. Various parameters such as plasma/fuel gas, plasma current, feedrate, feeding angle, type of feedstock (suspension or solution precursor), feedstock concentration, feedstock viscosity, solvent, etc. significantly influence the thermal and kinetic energy exchange between plasma/flame and feedstock material. Suspension plasma spray (SPS) and suspension high velocity oxy-fuel spray (SHVOF), once optimised, can give rise to coatings with multiscale features. An in-depth understanding of the complex interaction between feedstock solution/suspension chemical-physical properties and plasma/flame jet characteristics is essential to understand its specific impact on coating properties and their application. This paper presents comparisons between two different TiO2 coatings, deposited by SPS and S-HVOF, and obtained by varying some of the fundamental spray deposition parameters. The surface morphology and cross-sections of the as-deposited coatings were compared through SEM/EDX. Further, surface wetting properties were analysed through measuring the static and dynamic contact angles.