RESEARCH ON THE EFFECT OF PROTECTING COATING ON THE FIRE RESISTANCE OF ALUMINUM ALLOY STRUCTURES

S. Vovk, N. Ferents, D. Kharyshyn
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Abstract

Polyfunctional protective coatings based on filled polysiloxane compositions are technological and can be used to increase the fire resistance of metal structural materials due to high thermomechanical properties, which are determined by stable structural and phase composition. The influence of protective coatings on the basis of polysiloxane-filled oxide components on fire resistance of aluminum alloys is investigated in the work. The choice of the initial compositions for fire protection coatings was carried out with the aim of obtaining of expanded heat-insulating heatresistant layer on the surface of an aluminum alloy at temperatures of 473 K and higher. The methods of physico-chemical analysis have established that when heated more than 473 K as a result of thermo oxidative degradation of polysiloxane with the release of gaseous products, there is an expanding coating with the formation of a fire-proof porous heat-insulating layer on the surface of an aluminum alloy. The coefficient of expanding the coating is within the range of 9.8 ... 12.4. The reliability of the use of physicochemical criteria when choosing the component composition of the coating and the effectiveness of the fire protection function is estimated from the results of the test on the aluminum alloy AMG6 and on the model of its thermal conductivity. 20 Пожежна безпека, №34, 2019 A model of thermal conductivity of a protective coating is proposed, which consists of a layer that limits heat transfer through a two-layer wall. When exposed to the aluminum plate of the heat flow, it is heated to the depth of the coating, which leads to its expanding and the formation of a thermal barrier. The dynamics of temperature distribution during a fire on the protective coating of an aluminum alloy is predicted by simulating the heat transfer process in a homogeneous solid by a mathematical model. The theoretical and practical researches have established the dependence of the parameter of heating the protected aluminum alloy to the critical temperature, depending on the thickness of the coating. The presence on the surface of a protected alloy coating, based on the filled polysiloxane, changes the process of heat transfer to its surface, which increases the fire resistance of the structure by 3 ...4 times.
保护涂层对铝合金结构耐火性能影响的研究
基于填充型聚硅氧烷组合物的多功能防护涂层是一种技术技术,由于其具有稳定的结构和相组成所决定的高热机械性能,可用于提高金属结构材料的耐火性能。研究了基于聚硅氧烷填充氧化物组分的防护涂层对铝合金耐火性能的影响。对防火涂料的初始成分进行了选择,目的是在473 K及以上的温度下在铝合金表面获得膨胀隔热耐热层。物理化学分析的方法已经确定,当加热超过473 K时,由于聚硅氧烷的热氧化降解并释放气态产物,在铝合金表面形成一层膨胀的涂层,形成防火多孔隔热层。涂层的膨胀系数在9.8…12.4. 通过对铝合金AMG6及其导热系数模型的测试结果,估计了选用物化标准时涂层成分组成的可靠性和防火功能的有效性。20 Пожежна безпека,№34,2019提出了一种保护涂层的导热率模型,该模型由一层限制通过两层壁的传热的层组成。当接触到热流的铝板时,它被加热到涂层的深处,从而导致其膨胀并形成热障。通过建立数学模型,模拟均匀固体中的传热过程,预测了铝合金保护涂层着火时温度分布的动态规律。理论和实践研究已经建立了保护铝合金加热到临界温度的参数与涂层厚度的依赖关系。基于填充的聚硅氧烷的保护合金涂层表面的存在改变了其表面的传热过程,从而使结构的耐火性提高了3…4倍。
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