High pressure structural study of quasicrystalline AlMn

E. Johnson, J. Staun Olsen, J.V. Wood, L. Gerward
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引用次数: 9

Abstract

High pressure X-ray diffraction studies have been performed on rapidly solidified AlMn alloys (35 and 40 wt.% manganese) containing the quasicrystalline phase. Pressure experiments were undertaken using a diamond anvil cell, and X-ray diffraction analysis in the energy dispersive mode was performed using the synchrotron radiation facility at HASYLAB-DESY in Hamburg. Both the quasicrystalline phase and the AlMn α phase were found to have stable structures for pressures up to 47 GPa and they showed reversible behaviour for decreasing pressures. Using a Murnaghan-type equation of state, the best values of the bulk modulus and its pressure derivative for the icosahedral phase were found to be B0 = 146 GPa ∓ 10 GPa and B′0 = 1.7 ∓ 0.5 respectively. The bulk modulus and the pressure derivative for the α phase are B0 = 85 GPa ∓ 2GPa and B0 = 2.9 ∓ 0.1 respectively.

准晶AlMn的高压结构研究
高压x射线衍射研究了含有准晶相的快速凝固AlMn合金(35和40 wt.%锰)。利用金刚石砧细胞进行了压力实验,并在汉堡HASYLAB-DESY的同步辐射设备上进行了能量色散模式的x射线衍射分析。准晶相和AlMn α相在47gpa压力下均具有稳定的结构,并且在压力降低时表现出可逆的行为。利用murnaghan型状态方程,发现二十面体相的体积模量及其压力导数的最佳值分别为B0 = 146 GPa / 10 GPa和B0 = 1.7 0.5。α相的体积模量和压力导数分别为B0 = 85 GPa + 2GPa和B0′= 2.9 + 0.1。
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