The Results of Theoretical and Practical Studies of Flotation of Nanoscale Silicon Structures

V. V. Kondratyev, A. Karlina, A. A. Nemarov, N. Ivanov
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引用次数: 3

Abstract

This paper presents theoretical calculations and the results of laboratory experiments showing that almost all quartzite, carried away as a fine dust phase in gas removal and gas cleaning, presented spheroidized microand nanoparticles of SiO2. It takes the dust of gas purification from the class of “waste” in class “product” if carbon impurities, which invariably accompanies in a fine dust, will be removed. As a result of studying the properties of the dust production of silicon revealed that 85 % of it represented with spheroidized particles of SiO2, and the resulting amounts of dust makes a promising source for production. The best process for extracting the associated carbon nanotubes is flotation. Floating particles of micro and nano-sized particles should be carried out in a laminar flow of the pulp with the fewest basic flotation cycles. In the thick layer of watery foam microspheres and nanospheres of silica are washed away in the chamber of the product interbubble channels. Flotation air bubbles should be nano and micro size. Initial bubbles emerging from the aerator must be close to monodisperse distribution. The reagents used need to be more soluble in water than conventional. As the aerator should be used pneumohydraulic aerator. To activate hydrophilized particles of valuable component need to use pressure flotation. To reduce energy consumption and time of flotation need the smallest number of elementary cycles of flotation (ETSF). Before and after the flotation conglomerates of valuable component particles with other particles should be broken, as well as to make the necessary removal of impurities of the sand slurry. The results demonstrated that as a co-product along with the metallurgical silicon is formed a large amount of dust containing up to 85 % of spheroidized microand nanoparticles of silicon dioxide and up to 10 % carbon nanotube content and other nanoparticles. Enrichment product possible to 99.5 %. Further enrichment requires additional research.
纳米硅结构浮选的理论与实践研究结果
理论计算和室内实验结果表明,气体净化过程中作为细尘相带走的石英岩中,几乎所有石英岩中都含有球化的SiO2微粒和纳米颗粒。如果要去除微粒中始终伴随着的碳杂质,则需要从“废物”类别的“产品”类别中去除气体净化的粉尘。对硅粉尘产生的性质进行了研究,结果表明85%的硅粉尘为球化的SiO2颗粒,由此产生的粉尘量是一个很有前景的生产来源。浮选是提取伴生碳纳米管的最佳工艺。微细颗粒和纳米颗粒的浮选应在矿浆的层流中进行,基本浮选周期最少。在水泡沫层的厚层中,二氧化硅微球和纳米球在产物气泡间通道的腔室中被冲走。浮选气泡应达到纳米级和微微级。从曝气器中产生的初始气泡必须接近单分散分布。所用的试剂需要比传统试剂更易溶于水。由于曝气机应采用气液式曝气机。为了活化有价组分的亲水颗粒,需要采用压力浮选。为了减少浮选的能耗和时间,需要尽量减少浮选的基本循环次数。浮选前后的砾岩中有价值的组分颗粒应与其他颗粒一起破碎,以及对砂浆进行必要的杂质去除。结果表明,作为伴随冶金硅形成的副产物,大量粉尘中含有高达85%的球化二氧化硅微粒子和高达10%的碳纳米管和其他纳米粒子。浓缩产物可达99.5%。进一步的丰富需要进一步的研究。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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