Preparation and heat-moisture properties of phase change hygroscopic materials

Zhimin Wu, Zhi Chen, Menghao Qin
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Abstract

Orbit (02/10/2019) Preparation and heat-moisture properties of phase change hygroscopic materials A new composite phase change humidity material (CMPCM) was prepared, which has the functions of temperature regulation and humidity controlling. It was synthesized by composite microencapsulated phase change material (MPCM) and porous humidity control material. CMPCM can effectively stabilize the indoor temperature as well as humidity fluctuations, and reduce building energy consumption as a passive energy-saving material. The MPCM was synthesized by sol-gel method with a mixture of capric acid and octadecanoic acid (PCM) as core, and SiO2 as shell. The diatomite was selected as porous hygroscopic material. The performance of composition and structure, thermal properties, thermal stability, moisture transfer coefficient and moisture buffer value were characterized by scanning electron microscopy (SEM), differential scanning calorimetry (DSC), thermal gravimetric analysis (TGA), positive cup evaporation method and isothermal sorption method respectively. DSC and TGA results showed that the super-cooling degree of CMPCM was lower than that of PCM, and the initial degradation temperature of CMPCM was higher than that of PCM. Moisture Transfer Characteristics Test showed that the moisture transfer coefficient and moisture buffer value of CMPCM were higher than that of classical materials.
相变吸湿材料的制备及其热湿性能研究
制备了一种具有温度调节和湿度控制功能的新型复合相变吸湿材料(CMPCM)。采用复合微囊化相变材料(MPCM)和多孔调湿材料合成了微囊化相变材料。CMPCM作为一种被动式节能材料,可以有效地稳定室内温度和湿度波动,降低建筑能耗。以癸酸和十八烷酸(PCM)的混合物为核心,SiO2为壳层,采用溶胶-凝胶法制备了MPCM。选用硅藻土作为多孔吸湿材料。分别采用扫描电镜(SEM)、差示扫描量热法(DSC)、热重分析(TGA)、正杯蒸发法和等温吸附法对其组成结构、热性能、热稳定性、水分传递系数和水分缓冲值进行了表征。DSC和TGA结果表明,CMPCM的过冷度低于PCM,且CMPCM的初始降解温度高于PCM。水分传递特性试验表明,CMPCM的水分传递系数和水分缓冲值均高于经典材料。
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