Synthesis, Characterisation and Dissociation of a Glycinate Bridged Trinuclear Co(III)-Cu(II)-Co(III) Complex

BioInorganic Reaction Mechanisms Pub Date : 2003-01-01 DOI:10.1515/irm-2003-0109

Ν. N. Das, A. Dash, G. S. Brahama, P. Mohanty

引用次数: 0

Abstract

Abstract A trinuclear complex, [{(NH3)5Co(O2CCH2NH)}2Cu](ClO4)6.2H2O has been synthesised using mononuclear glycinato(pentaammine)cobalt(III) Perchlorate and characterised by various physicochemical methods. The kinetic study by stopped-flow spectrophotometer indicated that the dissociation of the trinuclear complex occurred mainly through an acid catalysed path.

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甘氨酸桥接三核Co(III)-Cu(II)-Co(III)配合物的合成、表征和解离

摘要以单核甘氨酸(五胺)钴(III)高氯酸盐为原料合成了[{(NH3)5Co(O2CCH2NH)}2Cu](ClO4)6.2H2O三核配合物，并用各种物理化学方法对其进行了表征。停流分光光度计的动力学研究表明，三核配合物的解离主要通过酸催化途径进行。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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BioInorganic Reaction Mechanisms

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