Quantification of coumarins, furocoumarins and polymethoxyflavones in hydroalcoholic fragrances by supercritical fluid chromatography‐tandem mass spectrometry

IF 2.2 3区农林科学 Q3 CHEMISTRY, APPLIED

Journal of Essential Oil Research Pub Date : 2023-07-17 DOI:10.1080/10412905.2023.2236626

Maria Rita Testa Camillo, M. Russo, A. Trozzi, L. Mondello, P. Dugo

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引用次数: 1

Abstract

ABSTRACT Citrus essential oils, thanks to their pleasant aroma, are certainly the most used ingredients in the formulation of hydroalcoholic fragrances. The non-volatile fraction of Citrus essential oil is composed for 10–20% of coumarins, furocoumarins and polymethoxyflavones. It is well known that furocoumarins induce photosensitization and have potential carcinogenic and mutagenic effects. It follows that furocoumarins levels in cosmetics product are constantly monitored by opinions and regulations issued by the International Fragrance Association. The aim of this research article was to quantify coumarins, furocoumarins and polymethoxyflavones in thirty commercial hydroalcoholic fragrances using supercritical fluid chromatography in combination with triple quadrupole mass spectrometry technique (SFC-QqQ-MS). According to author’s knowledge, this is the first report on the determination of oxygen heterocyclic compounds in hydroalcoholic fragrances by means of SFC-QqQ-MS technique.

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超临界流体色谱-串联质谱法定量分析水醇香精中的香豆素、呋喃香豆素和多甲氧基黄酮

柑橘精油，由于其令人愉悦的香气，当然是最常用的成分，在配制水酒精香水。柑橘精油的非挥发性部分由香豆素，呋喃香豆素和多甲氧基黄酮组成的10-20%。众所周知，呋喃香豆素可诱导光敏，并具有潜在的致癌和致突变作用。因此，国际香氛协会发布的意见和法规不断监测化妆品中呋喃香豆素的含量。采用超临界流体色谱-三重四极杆质谱联用技术(SFC-QqQ-MS)对30种市售水醇香精中的香豆素、呋喃香豆素和多甲氧基黄酮进行定量分析。据笔者所知，本文首次报道了用SFC-QqQ-MS技术测定水醇香精中氧杂环类化合物。

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来源期刊

Journal of Essential Oil Research 工程技术-食品科技

CiteScore

6.00

自引率

3.30%

发文量

审稿时长

18-36 weeks

期刊介绍： Journal of Essential Oil Research ( JEOR) is the major forum for the publication of essential oil research and analysis. Each issue includes studies performed on the chemical composition of some of the 20,000 aromatic plants known in the plant kingdom. JEOR is devoted entirely to all phases of research from every corner of the world by the experts in their field. JEOR''s main areas of focus include: -Analytical chemistry- Biological activity- Biotechnology- Chemical composition- Chemical synthesis- Chemosystematics- Microbiological activity- Plant biochemistry/biosynthesis- Toxicology. Published six times per year, JEOR provides articles on the aromatic principles of a plant or its isolates and are directed toward furthering our readers'' knowledge of the aromatic plant and animal kingdoms.