Nanocrystalline MgO powder materials prepared by sol-gel studied by X-ray diffraction and electron microscopy

Q2 Chemistry
G. Dercz, L. Paja̧k, K. Prusik, R. Pielaszek, J. Malinowski
{"title":"Nanocrystalline MgO powder materials prepared by sol-gel studied by X-ray diffraction and electron microscopy","authors":"G. Dercz, L. Paja̧k, K. Prusik, R. Pielaszek, J. Malinowski","doi":"10.1524/ZKSU.2009.0037","DOIUrl":null,"url":null,"abstract":"Materials with MgO nanocrystallites were prepared by sol-gel synthesis. Alcogels were dried either supercritically at 538 K or in supercritical CO2. Conventional drying was also applied. Structure studies were performed by X-ray diffraction, scanning and transmis- sion electron microcopies. Nitrogen adsorption/desorption measurements were also per- formed. Calcination of dry gels at 723 K under vacuum yielded MgO nanocrystallites. In the studied materials the presence of the amorphous phase was observed. It is also stated that MgO nanocrystallites are immersed in an amorphous matrix. Morphology of supercritically dried samples is similar; rough surface of powder particles is observed. Powder particles of conventionally dried sample are more compact. Size of MgO crystallites is generally similar for all samples and equal to about 7 nm despite the drying conditions of alcogels. The specific surface area and the volume of mesopores are the great- est for the sample supercritically dried at 538 K.","PeriodicalId":23897,"journal":{"name":"Zeitschrift Fur Kristallographie","volume":"46 1","pages":"255-260"},"PeriodicalIF":0.0000,"publicationDate":"2009-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"5","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Zeitschrift Fur Kristallographie","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1524/ZKSU.2009.0037","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"Chemistry","Score":null,"Total":0}
引用次数: 5

Abstract

Materials with MgO nanocrystallites were prepared by sol-gel synthesis. Alcogels were dried either supercritically at 538 K or in supercritical CO2. Conventional drying was also applied. Structure studies were performed by X-ray diffraction, scanning and transmis- sion electron microcopies. Nitrogen adsorption/desorption measurements were also per- formed. Calcination of dry gels at 723 K under vacuum yielded MgO nanocrystallites. In the studied materials the presence of the amorphous phase was observed. It is also stated that MgO nanocrystallites are immersed in an amorphous matrix. Morphology of supercritically dried samples is similar; rough surface of powder particles is observed. Powder particles of conventionally dried sample are more compact. Size of MgO crystallites is generally similar for all samples and equal to about 7 nm despite the drying conditions of alcogels. The specific surface area and the volume of mesopores are the great- est for the sample supercritically dried at 538 K.
用x射线衍射和电子显微镜研究了溶胶-凝胶法制备的纳米晶氧化镁粉末材料
采用溶胶-凝胶法制备了MgO纳米晶材料。乙醇在538 K下或在超临界CO2中进行超临界干燥。还采用了常规干燥。通过x射线衍射、扫描和透射电镜对其结构进行了研究。对氮的吸附/解吸也进行了测定。干凝胶在723 K真空下煅烧得到MgO纳米晶。在所研究的材料中观察到非晶相的存在。MgO纳米晶浸没在非晶基体中。超临界干燥样品的形貌相似;观察到粉末颗粒表面粗糙。常规干燥样品的粉末颗粒更致密。所有样品的MgO晶体尺寸大致相似,无论乙醇的干燥条件如何,其大小都在7 nm左右。在538 K超临界干燥时,样品的比表面积和介孔体积最大。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
CiteScore
1.47
自引率
0.00%
发文量
0
审稿时长
3 months
期刊介绍: Zeitschrift für Kristallographie International journal for structural, physical, and chemical aspects of crystalline materials ISSN 0044-2968 Founded in 1877 by Paul Groth Zeitschrift für Kristallographie is one of the world’s oldest scientific journals. In original papers, letters and review articles it presents results of theoretical or experimental study on crystallography.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信