Electrocatalytic Resorcinol Oxidation by Active Oxygen forms in Situ Generated in Conjugate Reactions on Pt and Pb/PbO₂ Anodes and Mesostructured Carbon Cathode СМК‑3

IF 0.5 Q4 CHEMISTRY, MULTIDISCIPLINARY

Journal of Siberian Federal University. Chemistry Pub Date : 2021-03-01 DOI:10.17516/1998-2836-0217

G. V. Kornienko, T. Kenova, V. L. Kornienko, A. Kukushkin

引用次数: 0

Abstract

Kinetics and selectivity of indirect electrocatalytic resorcinol oxidation by active oxygen forms (AOF) in situ generated from oxygen in gas diffusion electrode (GDE) mesostructured carbon CMK‑3 and Pt, Pb/PbO2 at different pH were studied. The high resorcinol oxidation process effectivity in both Pt-GDE at pH=10 (99 %) and Pb/PbO2 + Fe2+ at рН=2 (99 %) systems was shown; the resorcinol oxidation scheme was proposed

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Pt、Pb/PbO 2阳极和介结构碳阴极СМК‑3共轭反应中原位生成的活性氧电催化间苯二酚氧化

研究了气体扩散电极(GDE)介结构碳CMK‑3和Pt、Pb/PbO2在不同pH下原位生成的活性氧形式(AOF)间接电催化间苯二酚氧化的动力学和选择性。在pH=10 (99%) Pt-GDE和рН=2 (99%) Pb/PbO2 + Fe2+体系中，间苯二酚的氧化效果都很高;提出了间苯二酚氧化方案

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Journal of Siberian Federal University. Chemistry CHEMISTRY, MULTIDISCIPLINARY-

CiteScore

1.10

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0.00%

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