Novel intramolecular Michael-type reactions between vinyldiphenylphosphine and pentamethylcyclopentadienyl coordinated to rhodium(III): formation and X-ray structures of heptadentate 10-electron donor ligands

Journal of The Chemical Society, Chemical Communications Pub Date : 1995-01-01 DOI:10.1039/C39950001629

L. Barthel-Rosa, V. Catalano, J. H. Nelson

引用次数: 8

Abstract

The reaction between vinyldiphenylphosphine and [{(η5-C5Me5)RhCl2}2] proceeds via an intramolecular hydroalkyl addition to yield the two isomeric products 1aand 2a.

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乙烯基二苯基膦与五甲基环戊二烯配位铑(III)之间的新型分子内迈克尔型反应:七齿酸10电子给体的形成和x射线结构

乙烯基二苯基膦与[{(η - 5- c5me5)RhCl2}2]通过分子内加成反应生成两种异构体产物1a和2a。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Journal of The Chemical Society, Chemical Communications

自引率

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审稿时长

2 months