SINTESIS TiO2 TERDOPING Bi3+ DAN UJI AKTIVITAS FOTOKATALISIS ANTIBAKTERI E.coli DENGAN BANTUAN SINAR TAMPAK (SYNTHESIS OF Bi3+ DOPED TiO2 AND PHOTOCATALYSIS ACTIVITY TEST OF E.coli ANTIBACTERIA UNDER VISIBLE IRRADIATION)

Annisa Furqonita, A. B. Aritonang, M. A. Wibowo
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Abstract

The synthesis of Bi3+ doped TiO2 was carried out using the sol-gel method with the precursor solution of titanium tetraisopropoxide (TTiP). Bi3+ cation dopant is done to reduce the energy of the TiO2 band gap so that it can be active in the visible light region. The synthesized Bi(III) –TiO2 photocatalyst was characterized using DRS UV-Vis, FTIR, and EDX. The results of the DRS UV-Vis analysis showed that 1% Bi(III) –TiO2 photocatalyst had a bandgap energy of 2.79 eV or equivalent to a wavelength of 469.97 nm. Infrared spectra show that there is a unique absorption at the wave number 956,56 cm-1 which is the absorption of the vibration Bi-O-Ti group. Photocatalyst Bi(III) -TiO2 was then tested for antibacterial activity against E. coli in polluted water. The activity test was carried out using the turbidimetric method by UV-vis spectrophotometry. The results of the activity test for 120 minutes with the help of visible light showed that the photocatalyst Bi(III) –TiO21% had the best antibacterial activity. The decrease in the number of E. coli in the water reached 48.54%.
以四异丙醇钛(TTiP)为前驱体溶液,采用溶胶-凝胶法制备了Bi3+掺杂TiO2。Bi3+阳离子掺杂是为了降低TiO2带隙的能量,使其在可见光区活跃。采用DRS UV-Vis、FTIR和EDX对合成的Bi(III) -TiO2光催化剂进行了表征。DRS UV-Vis分析结果表明,1% Bi(III) -TiO2光催化剂的带隙能量为2.79 eV,相当于波长为469.97 nm。红外光谱表明,在波数956,56 cm-1处存在一个独特的吸收,这是振动Bi-O-Ti基团的吸收。然后测试了光催化剂Bi(III) -TiO2对污染水中大肠杆菌的抗菌活性。采用紫外-可见分光光度浊度法进行活性测定。可见光下120 min的活性测试结果表明,光催化剂Bi(III) -TiO21%具有最佳的抗菌活性。水中大肠杆菌数量减少48.54%。
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