Aerobic epoxidation of olefins catalyzed by polymerizable β-ketoesterate complexes of iron(III), nickel(II) and cobalt(II)

Q4 Chemical Engineering

分子催化 Pub Date : 1994-11-13 DOI:10.1016/0304-5102(94)87026-8

P. Mastrorilli, C.F. Nobile

引用次数: 22

Abstract

Efficient epoxidation of olefinic compounds is achieved by using soluble polymerizable β-ketoesterate complexes. Iron(III), cobalt(II) and nickel(II) catalytic centres are utilized in 1,2-dichloroethane at ambient conditions. Oxygen or air and a branched aldehyde are employed as the oxidant and reductant respectively (Mukaiyama's conditions).

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铁(III)、镍(II)和钴(II)可聚合β-酮酯配合物催化烯烃有氧环氧化反应

烯烃化合物的高效环氧化是通过使用可溶解的可聚合β-酮酯配合物来实现的。铁(III)、钴(II)和镍(II)催化中心在环境条件下用于1,2-二氯乙烷。氧或空气和支醛分别作为氧化剂和还原剂(Mukaiyama条件)。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

分子催化 Chemical Engineering-Catalysis

CiteScore

1.50

自引率

0.00%

发文量

2959

期刊介绍： Journal of Molecular Catalysis (China) is a bimonthly journal, founded in 1987. It is a bimonthly journal, founded in 1987, sponsored by Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, under the supervision of Chinese Academy of Sciences, and published by Science Publishing House, which is a scholarly journal openly circulated both at home and abroad. The journal mainly reports the latest progress and research results on molecular catalysis. It contains academic papers, research briefs, research reports and progress reviews. The content focuses on coordination catalysis, enzyme catalysis, light-ribbed catalysis, stereochemistry in catalysis, catalytic reaction mechanism and kinetics, the study of catalyst surface states and the application of quantum chemistry in catalysis. We also provide contributions on the activation, deactivation and regeneration of homogeneous catalysts, solidified homogeneous catalysts and solidified enzyme catalysts in industrial catalytic processes, as well as on the optimisation and characterisation of catalysts for new catalytic processes. The main target readers are scientists and postgraduates working in catalysis in research institutes, industrial and mining enterprises, as well as teachers and students of chemistry and chemical engineering departments in colleges and universities. Contributions from related professionals are welcome.