{"title":"Lithium Isotope Geochemistry","authors":"S. Penniston‐Dorland, Xiao-Ming Liu, R. Rudnick","doi":"10.2138/RMG.2017.82.6","DOIUrl":null,"url":null,"abstract":"The lithium isotope system is increasingly being applied to a variety of Earth science studies, as the burgeoning literature attests; over 180 papers have been published in the last twelve years that report lithium isotope data, including five review papers that cover different aspects of lithium isotope applications (Elliott et al. 2004; Tomascak 2004; Tang et al. 2007b; Burton and Vigier 2011; Schmitt et al. 2012), and a book (Tomascak et al. 2016). The upswing in lithium isotope studies over the past decade reflects analytical advances that have made Li measurements readily obtainable. These include the use of multi-collector inductively coupled plasma mass spectrometry (MC-ICP-MS) for relatively precise solution measurements (Tomascak et al. 1999a) and secondary ion mass spectrometry (SIMS) for high spatial resolution measurements (Chaussidon and Robert 1998; Kasemann et al. 2005; Bell et al. 2009). In addition, lithium isotope studies are motivated by the large variety of problems for which they may provide insight, including crust–mantle recycling, silicate weathering, fluid–rock interaction, as well as geospeedometry. The great interest in the Li system that spurred the development of these new analytical methods was initiated by the pioneering work of Lui-Heung Chan, who demonstrated not only that Li isotopic fractionation can be very large at or near the Earth’s surface (Chan and Edmond 1988), but also that Li isotopes are strongly fractionated during seawater-basalt interaction (Chan et al. 1992). This discovery naturally led to the search for a recycled slab signature in Li isotopes of arc lavas (some of the earlier studies include Moriguti and Nakamura 1998a; Chan et al. 1999, 2002b; Tomascak et al. 2000, 2002; Leeman et al. 2004; Moriguti et al. 2004), as well as more deeply derived intraplate basalts (e.g., Chan and Frey 2003 …","PeriodicalId":49624,"journal":{"name":"Reviews in Mineralogy & Geochemistry","volume":"9 1","pages":"165-217"},"PeriodicalIF":0.0000,"publicationDate":"2017-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"152","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Reviews in Mineralogy & Geochemistry","FirstCategoryId":"89","ListUrlMain":"https://doi.org/10.2138/RMG.2017.82.6","RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"Earth and Planetary Sciences","Score":null,"Total":0}
引用次数: 152
Abstract
The lithium isotope system is increasingly being applied to a variety of Earth science studies, as the burgeoning literature attests; over 180 papers have been published in the last twelve years that report lithium isotope data, including five review papers that cover different aspects of lithium isotope applications (Elliott et al. 2004; Tomascak 2004; Tang et al. 2007b; Burton and Vigier 2011; Schmitt et al. 2012), and a book (Tomascak et al. 2016). The upswing in lithium isotope studies over the past decade reflects analytical advances that have made Li measurements readily obtainable. These include the use of multi-collector inductively coupled plasma mass spectrometry (MC-ICP-MS) for relatively precise solution measurements (Tomascak et al. 1999a) and secondary ion mass spectrometry (SIMS) for high spatial resolution measurements (Chaussidon and Robert 1998; Kasemann et al. 2005; Bell et al. 2009). In addition, lithium isotope studies are motivated by the large variety of problems for which they may provide insight, including crust–mantle recycling, silicate weathering, fluid–rock interaction, as well as geospeedometry. The great interest in the Li system that spurred the development of these new analytical methods was initiated by the pioneering work of Lui-Heung Chan, who demonstrated not only that Li isotopic fractionation can be very large at or near the Earth’s surface (Chan and Edmond 1988), but also that Li isotopes are strongly fractionated during seawater-basalt interaction (Chan et al. 1992). This discovery naturally led to the search for a recycled slab signature in Li isotopes of arc lavas (some of the earlier studies include Moriguti and Nakamura 1998a; Chan et al. 1999, 2002b; Tomascak et al. 2000, 2002; Leeman et al. 2004; Moriguti et al. 2004), as well as more deeply derived intraplate basalts (e.g., Chan and Frey 2003 …
锂同位素系统越来越多地应用于各种地球科学研究,正如新兴文献所证明的那样;在过去的12年中,已经发表了180多篇报告锂同位素数据的论文,其中包括5篇综述论文,涵盖了锂同位素应用的不同方面(Elliott et al. 2004;Tomascak 2004;Tang et al. 2007b;Burton and Vigier 2011;Schmitt et al. 2012)和一本书(Tomascak et al. 2016)。在过去的十年里,锂同位素研究的上升反映了分析的进步,使得锂的测量很容易获得。其中包括使用多收集器电感耦合等离子体质谱法(MC-ICP-MS)进行相对精确的溶液测量(Tomascak等人,1999a)和二次离子体质谱法(SIMS)进行高空间分辨率测量(Chaussidon和Robert 1998;Kasemann et al. 2005;Bell et al. 2009)。此外,锂同位素研究的动力来自于它们可能提供见解的各种各样的问题,包括地壳-地幔再循环、硅酸盐风化、流体-岩石相互作用以及地质速度测量。Li - heung Chan的开创性工作引发了人们对Li体系的极大兴趣,促使这些新分析方法的发展,他不仅证明了Li同位素在地球表面或接近地球表面的分馏程度非常大(Chan和Edmond 1988),而且证明了Li同位素在海水-玄武岩相互作用过程中分馏程度很强(Chan et al. 1992)。这一发现自然导致了在弧熔岩的Li同位素中寻找再循环板的特征(早期的一些研究包括Moriguti和Nakamura 1998a;Chan et al. 1999,2002b;Tomascak et al. 2000, 2002;Leeman et al. 2004;Moriguti et al. 2004),以及更深层衍生的板内玄武岩(例如,Chan和Frey 2003……
期刊介绍:
RiMG is a series of multi-authored, soft-bound volumes containing concise reviews of the literature and advances in theoretical and/or applied mineralogy, crystallography, petrology, and geochemistry. The content of each volume consists of fully developed text which can be used for self-study, research, or as a text-book for graduate-level courses. RiMG volumes are typically produced in conjunction with a short course but can also be published without a short course. The series is jointly published by the Mineralogical Society of America (MSA) and the Geochemical Society.