Grand Projection State: A Single Microscopic State to Determine Free Energy

Tetsuya Taikei, T. Kishimoto, Kazuhito Takeuchi, Koretaka Yuge
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Abstract

Recently, we clarify connection of spatial constraint and equilibrium macroscopic properties in disordered states of classical system under the fixed composition; namely few special microscopic states, independent of constituent elements, can describe macroscopic properties. In this study, we extend our developed approach to composition-unfixed system. Through this extension in binary system, we discover a single special microscopic state to determine not only composition but also Helmholtz free energy measured from unary system, which has not been described by a single state.
大投射态:决定自由能的单一微观态
最近,我们澄清了经典系统在固定组成下无序状态下的空间约束与平衡宏观性质的联系;即很少有特殊的微观状态,独立于组成元素,可以描述宏观性质。在本研究中,我们将我们发展的方法扩展到非固定成分系统。通过在二元系统中的推广,我们发现了一个单一的特殊微观状态,它不仅可以确定二元系统的组成,还可以确定一元系统中测量到的亥姆霍兹自由能,这是单一状态所不能描述的。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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