Investigation of Metal Oxide Nanoparticles by Using Punica granatum Extract

Malik Saif Ur Rehman, Awais Shahid Minhas, Abdul Rehman, Mansoor A Baluch, Malik Sajjad Mehmood
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Abstract

Zinc oxide has significant importance as it has various applications in many industries due to its versatile properties which can be enhanced by production at the Nanoscale. Major applications of ZnO in material science are due to its greater refractive index value, considerable thermal conductivity, binding, biocompatibility, and anti-bacterial characteristics. Many physical and chemical Synthesis techniques are adopted but along with synthesis, these methods carry impurities that lead to a reduction of yield of pure Nanoparticles. Adoption of a sustainable route i.e. Green route for the synthesis of Nanoparticles considerably enhances the properties and effectiveness of NP’s, as it is a less hazardous method than other chemical and physical methods. Zinc oxide NPs have been successfully prepared by green synthesis using biological substrate (Fresh Punica granatum seed). Characterization techniques i.e. XRD, DRS, FTIR, UV reveals crystalline structure, Band Gap, Transmission, and absorption spectra of the sample. Miller indices values from the XRD plot are (100) (002) (101). The average grain size obtained from XRD analysis is 17nm and crystal geometry is hexagonal. Grain size ranges from 15nm to 40nm can have the best effect for antibacterial and antifungal applications. Bandgap energy shows the semiconductor range of ZnO Nanoparticles.
石榴提取物制备金属氧化物纳米颗粒的研究
氧化锌具有非常重要的意义,因为它在许多行业中具有各种应用,因为它具有多种特性,可以通过纳米级生产来增强。氧化锌在材料科学中的主要应用是由于其较大的折射率值,可观的导热性,结合性,生物相容性和抗菌特性。采用了许多物理和化学合成技术,但随着合成,这些方法携带杂质,导致纯纳米颗粒的产量降低。采用可持续的路线,即绿色路线合成纳米粒子,大大提高了纳米粒子的性能和有效性,因为它是一种比其他化学和物理方法危害更小的方法。以新鲜石榴籽为生物基质,采用绿色合成方法成功制备了氧化锌纳米粒子。表征技术,即XRD, DRS, FTIR, UV揭示了样品的晶体结构,带隙,透射和吸收光谱。XRD图米勒指数为(100)(002)(101)。XRD分析得到的平均晶粒尺寸为17nm,晶体几何形状为六边形。粒径在15nm ~ 40nm之间,抗菌、抗真菌效果最好。带隙能显示ZnO纳米颗粒的半导体范围。
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