{"title":"Decay sequences - ionic series of mass spectra for 2,4,6-tris(perfluoroalkyl)-1,3,5-triazines","authors":"Nikolay D. Kagramanov","doi":"10.17677/fn20714807.2023.04.02","DOIUrl":null,"url":null,"abstract":": This report presents the ion series of mass spectra for eight homologues of 2,4,6-tris(perfluoroalkyl)-1,3,5-triazines from NIST libraries, including the ion series of two isomers: triazine (C 3 F 7 ) 3 C 3 N 3 with symmetrical substituents C 3 F 7 and triazine (CF 3 ) 2 C 3 N 3 (C 7 F 15 ) with unsymmetrical substituent C 7 F 15 . The influence of molecular weight of substituents and their symmetry on fragmentation of 1,3,5-triazines is discussed. Using [(CF 3 ) 3 CO] 3 C 3 N 3 homologue with oxaperfluoroalkyl substituents as an example, the effect of (CF 3 ) 3 C groups and oxygen atoms on fragmentation is discussed","PeriodicalId":12217,"journal":{"name":"Fluorine Notes","volume":"396 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2023-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Fluorine Notes","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.17677/fn20714807.2023.04.02","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
: This report presents the ion series of mass spectra for eight homologues of 2,4,6-tris(perfluoroalkyl)-1,3,5-triazines from NIST libraries, including the ion series of two isomers: triazine (C 3 F 7 ) 3 C 3 N 3 with symmetrical substituents C 3 F 7 and triazine (CF 3 ) 2 C 3 N 3 (C 7 F 15 ) with unsymmetrical substituent C 7 F 15 . The influence of molecular weight of substituents and their symmetry on fragmentation of 1,3,5-triazines is discussed. Using [(CF 3 ) 3 CO] 3 C 3 N 3 homologue with oxaperfluoroalkyl substituents as an example, the effect of (CF 3 ) 3 C groups and oxygen atoms on fragmentation is discussed