M.John Plater , Mark R St J. Foreman , Thomas Gelbrich , Michael B Hursthouse
{"title":"Synthesis and characterisation of infinite coordination networks with 1,6-bis(4-pyridyl)hexane and copper nitrate","authors":"M.John Plater , Mark R St J. Foreman , Thomas Gelbrich , Michael B Hursthouse","doi":"10.1016/S1463-0184(01)00024-7","DOIUrl":null,"url":null,"abstract":"<div><p>Crystallisation of 1,6-bis(4-pyridyl)hexane (Py<sub>2</sub>C<sub>6</sub>H<sub>12</sub>) with copper nitrate gives two different phases. Phase <strong>1</strong> of composition [Cu(Py<sub>2</sub>C<sub>6</sub>H<sub>12</sub>)<sub>3</sub>(NO<sub>3</sub>)<sub>2</sub>]·2[Cu(Py<sub>2</sub>C<sub>6</sub>H<sub>12</sub>)<sub>2</sub>(H<sub>2</sub>O)(NO<sub>3</sub>)]·2(NO<sub>3</sub><span>)·EtOH consists of two different infinite chains in a 1:2 ratio that are interlocked. Hydrogen bonds link chains </span><em>I</em> to <em>II</em> and chains <em>II</em> to <em>II</em>. In contrast phase <strong>2</strong> of composition [Cu<sub>2</sub>(Py<sub>2</sub>C<sub>6</sub>H<sub>12</sub>)<sub>4</sub>(H<sub>2</sub>O)<sub>2</sub>]·(NO<sub>3</sub>)<sub>4</sub>·(Py<sub>2</sub>C<sub>6</sub>H<sub>12</sub>)·(EtOH)·2(H<sub>2</sub>O) is based upon an infinite 3D framework. It consists of four interpenetrating 3D networks that are crystallographically equivalent.</p></div>","PeriodicalId":10766,"journal":{"name":"Crystal Engineering","volume":"4 4","pages":"Pages 319-328"},"PeriodicalIF":0.0000,"publicationDate":"2001-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S1463-0184(01)00024-7","citationCount":"25","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Crystal Engineering","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1463018401000247","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 25
Abstract
Crystallisation of 1,6-bis(4-pyridyl)hexane (Py2C6H12) with copper nitrate gives two different phases. Phase 1 of composition [Cu(Py2C6H12)3(NO3)2]·2[Cu(Py2C6H12)2(H2O)(NO3)]·2(NO3)·EtOH consists of two different infinite chains in a 1:2 ratio that are interlocked. Hydrogen bonds link chains I to II and chains II to II. In contrast phase 2 of composition [Cu2(Py2C6H12)4(H2O)2]·(NO3)4·(Py2C6H12)·(EtOH)·2(H2O) is based upon an infinite 3D framework. It consists of four interpenetrating 3D networks that are crystallographically equivalent.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
