Volumetric and viscometric properties of aqueous 1,2-dimethylethylenediamine solution for carbon capture application

IF 4.2 Q2 ENERGY & FUELS
Hossein Haghani , Teerawat Sema , Pipat Na Ranong , Thanthip Kiattinirachara , Benjapon Chalermsinsuwan , Hongxia Gao , Zhiwu Liang , Paitoon Tontiwachwuthikul
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引用次数: 0

Abstract

The present work investigates the volumetric and viscometric properties of an aqueous solution of 1,2-dimethylethylenediamine (DEEDA) over an entire concentration range and an absorber operating temperature range of 313.15K–333.15K at atmospheric pressure. The investigated volumetric properties included the density, excess molar volume, partial molar volume, and the investigated viscometric properties included the viscosity, viscosity deviation, free energy for activation of viscous flow, excess free energy for activation of viscous flow, and excess entropy for activation of viscous flow. The results indicated that there are strong intermolecular interactions and suitable molecular packing in the binary DEEDA–water mixture. Hence, the mixture was found to deviate from a real mixture according to the calculated excess properties. The DEEDA solvent's preliminary volumetric and viscometric properties revealed convincing potential as a novel amine for carbon capture. Additionally, the Redlich-Kister-based correlations showed favorable correlative performance for excess molar volume, viscosity deviation, and excess entropy for activation of viscous flow.

用于碳捕获的 1,2-二甲基乙二胺水溶液的体积和粘度特性
本研究调查了 1,2-二甲基乙二胺(DEEDA)水溶液在整个浓度范围和吸收器工作温度范围 313.15K-333.15K 大气压力下的体积和粘度特性。考察的体积特性包括密度、过量摩尔体积、部分摩尔体积,考察的粘度特性包括粘度、粘度偏差、激活粘流的自由能、激活粘流的过量自由能和激活粘流的过量熵。结果表明,二元 DEEDA-水混合物中存在强烈的分子间相互作用和适当的分子堆积。因此,根据计算的过量特性,发现该混合物偏离了真实混合物。DEEDA 溶剂的初步体积和粘度特性显示了其作为一种新型胺用于碳捕获的令人信服的潜力。此外,基于 Redlich-Kister 的相关性表明,过量摩尔体积、粘度偏差和过量熵对激活粘性流动具有良好的相关性。
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来源期刊
Petroleum
Petroleum Earth and Planetary Sciences-Geology
CiteScore
9.20
自引率
0.00%
发文量
76
审稿时长
124 days
期刊介绍: Examples of appropriate topical areas that will be considered include the following: 1.comprehensive research on oil and gas reservoir (reservoir geology): -geological basis of oil and gas reservoirs -reservoir geochemistry -reservoir formation mechanism -reservoir identification methods and techniques 2.kinetics of oil and gas basins and analyses of potential oil and gas resources: -fine description factors of hydrocarbon accumulation -mechanism analysis on recovery and dynamic accumulation process -relationship between accumulation factors and the accumulation process -analysis of oil and gas potential resource 3.theories and methods for complex reservoir geophysical prospecting: -geophysical basis of deep geologic structures and background of hydrocarbon occurrence -geophysical prediction of deep and complex reservoirs -physical test analyses and numerical simulations of reservoir rocks -anisotropic medium seismic imaging theory and new technology for multiwave seismic exploration -o theories and methods for reservoir fluid geophysical identification and prediction 4.theories, methods, technology, and design for complex reservoir development: -reservoir percolation theory and application technology -field development theories and methods -theory and technology for enhancing recovery efficiency 5.working liquid for oil and gas wells and reservoir protection technology: -working chemicals and mechanics for oil and gas wells -reservoir protection technology 6.new techniques and technologies for oil and gas drilling and production: -under-balanced drilling/gas drilling -special-track well drilling -cementing and completion of oil and gas wells -engineering safety applications for oil and gas wells -new technology of fracture acidizing
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