Thermodynamics and Kinetics of Adoption of Ag (I) on Paramagnetic Silica Rice Husk Ash Surface

Wardian Antoni, S. Hamdiani, S. Kamali
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引用次数: 1

Abstract

Synthesis of paramagnetic silica from rice husk ash has been carried out as an adsorbent for heavy metal Ag (I). This study tried to synthesis and characterized the thermodynamics and kinetics behaviour of paramagnetic silica from the husk ash as metal adsorbent Ag (I). Determination of optimal conditions for adsorption of metal ions Ag (I) is carried out by varying the pH, concentration, and contact time of the adsorbent. The results showed that the optimum pH was at pH 3, optimal concentration Ag(I) of 350 ppm and optimal contact time of 90 minutes. At optimal conditions, paramagnetic silica adsorption capacity for metal ion Ag (I) is 323.62 mg/g. The isotherm model that is suitable for paramagnetic silica is the Freundlich isotherm model. The kinetic model that is suitable for paramagnetic silica is the Pseudo Order 2 kinetic model.
银(I)在顺磁性稻壳灰分表面吸附的热力学和动力学
利用稻壳灰合成顺磁二氧化硅作为重金属Ag (I)的吸附剂。本研究试图合成并表征稻壳灰顺磁二氧化硅作为金属吸附剂Ag (I)的热力学和动力学行为。通过改变吸附剂的pH、浓度和接触时间来确定吸附金属离子Ag (I)的最佳条件。结果表明,最佳pH为pH 3,最佳Ag(I)浓度为350 ppm,最佳接触时间为90 min。在最佳条件下,顺磁二氧化硅对金属离子Ag (I)的吸附量为323.62 mg/g。适用于顺磁性二氧化硅的等温线模型是Freundlich等温线模型。适合顺磁性二氧化硅的动力学模型是拟2级动力学模型。
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