A. Adawiah, Muhammad Shofyan Gunawan, I. Aziz, Wulandari Oktavia
{"title":"Synthesis of Bimetallic Metal-Organic Frameworks (MOFs) La-Y-PTC for Enhanced Dyes Photocatalytic Degradation","authors":"A. Adawiah, Muhammad Shofyan Gunawan, I. Aziz, Wulandari Oktavia","doi":"10.9767/bcrec.16130","DOIUrl":null,"url":null,"abstract":"Metal-Organic Frameworks (MOFs) is widely utilized as photocatalysts in dye photocatalytic degradation. This study successfully synthesized bimetallic MOFs La-Y-PTC by the solvothermal method. The synthesized La-Y-PTC has a diffractogram pattern with a value of 2θ = 5.69°; 9.57°; 16.8°; 20.05°; 24.8°; 26.15°; 29.77° and 41.93° with a crystal size of 21.45 nm. The La-Y-PTC has symmetric and asymmetric (COO−) at 1591 and 1433 cm−1, La−O and Y−O groups at 596 and 659 cm−1 and a band gap energy of 2.16 eV. Scanning Electron Microscope analysis showed that the morphology of La-Y-PTC is spherical with a particle size of 354.307 nm. La-Y-PTC degrades methylene blue and methyl orange at pH 2 with a degradation efficiency of 69.57% and 93.63%, respectively, under 250 watts of mercury lamp irradiation for 180 min with hydroxyl radical species as a dominant species that play a role in methylene blue and methyl orange degradations. Copyright © 2023 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).","PeriodicalId":9366,"journal":{"name":"Bulletin of Chemical Reaction Engineering & Catalysis","volume":"5 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2023-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Bulletin of Chemical Reaction Engineering & Catalysis","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.9767/bcrec.16130","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
用于增强染料光催化降解的双金属金属有机骨架La-Y-PTC的合成
金属有机骨架(MOFs)作为光催化剂在染料光催化降解中得到了广泛应用。本研究成功地采用溶剂热法合成了双金属mof La-Y-PTC。合成的La-Y-PTC的衍射图为2θ = 5.69°;9.57°;16.8°;20.05°;24.8°;26.15°;29.77°和41.93°,晶体尺寸为21.45 nm。La-Y- ptc在1591和1433 cm−1处有对称和不对称(COO−)基团,在596和659 cm−1处有La−O和Y−O基团,带隙能量为2.16 eV。扫描电镜分析表明,La-Y-PTC形貌为球形,粒径为354.307 nm。在250瓦汞灯照射180 min的条件下,La-Y-PTC对pH为2的亚甲基蓝和甲基橙的降解效率分别为69.57%和93.63%,其中羟基自由基为优势种,在亚甲基蓝和甲基橙的降解中起作用。版权所有©2023作者,BCREC集团出版。这是一篇基于CC BY-SA许可(https://creativecommons.org/licenses/by-sa/4.0)的开放获取文章。
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