Determination of organic phosphorus pesticide in environmental water by flow injection-spectrophotometry

Xinfeng Xiao, Qiang Zhang, Yuan Tian, Zhaoli Wang
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Abstract

An automatic, convenient method combined flow injection technique for determining organic phosphorus pesticide in environment water was developed based on the inhibition effects of organic phosphorus pesticide to plant-esterase. The optimized determining conditions were acquired, and the analytical characteristics of this method were studied. The linear ranges of dichlorvos' standard curves was 0.008 ∼ 4mg/L. The linear equation of dichlorvos was U(mV) = −4874.4 C (mg/L) + 110313. The correlation coefficient of dichlorvos was 0.9984. The detection limit (S/N= 3) was 0.02mg/L for dichlorvos. The relative standard deviation (RSD) of dichlorvos was 1.04% (n=6). The recoveries ranged from 95% to 105%. The analysis result was good.
流动注射-分光光度法测定环境水中有机磷农药
基于有机磷农药对植物酯酶的抑制作用,建立了一种自动简便的环境水中有机磷农药联合流动注射测定方法。获得了最佳的测定条件,并对该方法的分析特性进行了研究。敌敌畏标准曲线的线性范围为0.008 ~ 4mg/L。敌敌畏的线性方程为U(mV) =−4874.4 C (mg/L) + 110313。敌敌畏的相关系数为0.9984。敌敌畏的检出限(S/N= 3)为0.02mg/L。敌敌畏相对标准偏差(RSD)为1.04% (n=6)。加样回收率为95% ~ 105%。分析结果良好。
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