Conversion of Steel Converter Slag into HCl Gas Scavenger Using Alkali Fusion

T. Wajima
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Abstract

Steel converter slag, a by-product of iron- and steel-making plants, was converted into a hydrogarnet-containing product using the alkali fusion method. The converter slag was transformed into an alkali-fused slag with reactive phases via alkali fusion using sodium hydroxide at 600°C for 6 h, after which the fused slag was stirred in distilled water at ambient temperature to prepare a precursor to synthesize a product, comprising hydrogarnet, by heating the precursor at 80°C. This product could remove HCl gas at a high temperature (800°C) and showed higher Cl fixation than slag and lime. These results suggest that a novel product capable of removing HCl gas at high temperatures can be synthesized from converter slag via alkali fusion.
用碱熔法将钢转炉渣转化为HCl气体清除剂
采用碱熔法将炼钢厂副产转炉炉渣转化为含氢石榴石产品。转炉炉渣经氢氧化钠在600℃下碱熔6 h,转化为具有反应相的碱熔渣,熔渣在蒸馏水中常温搅拌,在80℃下加热制备前驱体,合成含水石榴石的产物。该产品在高温(800℃)下可脱除HCl气体,且Cl固着率高于炉渣和石灰。上述结果表明,利用转炉炉渣进行碱熔可以合成一种能够在高温下去除HCl气体的新型产品。
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