Action of N-bromosuccinimide on methine carbons of N,N′-bis(benzoylacetone)ethylenediaminatonickel(II) and -copper(II)

Takeo Nagahara, Kuninobu Kasuga, Yasuo Yamamoto
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引用次数: 6

Abstract

By the action of N-bromosuccinimide on ,N′-bis(benzoylacetone)ethylene-diamine complexes of nickel(II) and copper(II), both the bromo and succinimido substitutions on methine carbons occured. Three products were simultaneously obtained: dibromo-, bromo-succinimido-, and disuccinimido substituted complexes.

N-溴代琥珀酰亚胺对N,N ' -双(苯甲酰丙酮)乙二氨基镍(II)和-铜(II)的甲基碳的作用
通过N-溴代琥珀酰亚胺对镍(II)和铜(II)的N ' -双(苯甲酰丙酮)乙二胺配合物的作用,甲基碳上的溴代和琥珀酰亚胺都发生了取代。同时得到三种产物:二溴、溴-琥珀酰亚胺和二琥珀酰亚胺取代配合物。
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