Quality Characteristics and Αlpha-Tocopherol Content of Shea Butter Samples from Selected Markets Within Three Southwestern States of Nigeria

O. Adejumo, Temilade Arinola Edun, A. Kolapo, Olatunde Adekunle Ayodele
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Abstract

Shea (Vitellaria paradoxa) butter samples from selected markets in Nigeria were analyzed for AOAC quality characteristics and α-tocopherol content. The α-tocopherol was determined by RP-HPLC and mg per serving and % daily values (% DV) were estimated. The ranges of acid value (AV) [mgKOH/kg], free fatty acid (FFA) [%], peroxide value (PV) [meqO2/Kg], iodine value (IV) [gI2/100g] and saponification value (SV) [mgKOH/g] were 2.20- 2.59, 1.15-1.30, 0.75-0.95, 44.43-47.85 and 170.08-259.30, respectively. The -tocopherol had a retention time of 3.561 minutes and its content ranged from 1.15-2.60 mg/100 g in the samples, but 5.25 mg/100 g for the laboratory sample. Milligram (mg) per serving and percentage dietary value were 0.16-0.74 and 1.07-4.93, respectively. Quality characteristics varied significantly (p < 0.05) both within and across different markets. Based on the PV and IV results, the marketed shea butter samples may be both food and industry-grade but failed the FFA test. Similarly, 40% of samples did not qualify for domestic consumption and food industry applications. Hence, the samples with <5% DV values cannot serve as dietary sources of α-tocopherol. Dhaka Univ. J. Pharm. Sci. 21(2): 105-115, 2022 (December)
尼日利亚西南部三个州选定市场的乳木果油样品的品质特征及Αlpha-Tocopherol含量
选取尼日利亚市场的乳木果(Vitellaria paradoxa)黄油样品,分析其AOAC品质特征和α-生育酚含量。采用反相高效液相色谱法测定α-生育酚含量,并测定其毫克/份和%日摄取量(% DV)。酸值(AV) [mgKOH/kg]、游离脂肪酸(FFA)[%]、过氧化值(PV) [meqO2/ kg]、碘值(IV) [gI2/100g]和皂化值(SV) [mgKOH/g]的取值范围分别为2.20 ~ 2.59、1.15 ~ 1.30、0.75 ~ 0.95、44.43 ~ 47.85和170.08 ~ 259.30。-生育酚在样品中的含量为1.15 ~ 2.60 mg/100 g,在实验室样品中的含量为5.25 mg/100 g,保留时间为3.561 min。毫克(mg)每份和百分比膳食价值分别为0.16-0.74和1.07-4.93。质量特征在不同市场内部和不同市场之间差异显著(p < 0.05)。根据PV和IV的结果,市场上销售的乳木果油样品可能是食品级和工业级,但没有通过FFA测试。同样,40%的样品不符合国内消费和食品工业应用的要求。因此,DV值<5%的样品不能作为α-生育酚的膳食来源。达卡大学药学院。科学21(2):105-115,2022(12月)
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