Giovanna Vezzalini, Simona Quartieri, Ermanno Galli, Alberto Alberti, Giuseppe Cruciani, Ake Kvick
{"title":"Crystal structure of the zeolite mutinaite, the natural analog of ZSM-5","authors":"Giovanna Vezzalini, Simona Quartieri, Ermanno Galli, Alberto Alberti, Giuseppe Cruciani, Ake Kvick","doi":"10.1016/S0144-2449(97)00124-3","DOIUrl":null,"url":null,"abstract":"<div><p>We describe the crystal structure of the high-silica zeolite mutinaite, recently found at Mt. Adamson (Northern Victoria Land, Antarctica). Mutinaite is the natural counterpart of the synthetic zeolite ZSM-5. The new mineral, (Na<sub>2.76</sub>K<sub>0.11</sub>Mg<sub>0.21</sub>Ca<sub>3.78</sub>) (Al<sub>11.20</sub>Si<sub>84.91</sub>) · 6O H<sub>2</sub>O H<sub>2</sub>O, is orthorhombic, space group Pnma, with <em>a</em> = 20.201(2), <em>b</em> = 19.991(2), and <em>c</em> = 13.469(2) Å. A single-crystal X-ray diffraction experiment was performed at the synchrotron radiation source ESRF (Grenoble). No Si-Al order in the framework has been detected. Large distances between ions in the channels and framework oxygens suggest weak interactions between the framework and extraframework species.</p></div>","PeriodicalId":23983,"journal":{"name":"Zeolites","volume":"19 5","pages":"Pages 323-325"},"PeriodicalIF":0.0000,"publicationDate":"1997-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S0144-2449(97)00124-3","citationCount":"55","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Zeolites","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0144244997001243","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 55
Abstract
We describe the crystal structure of the high-silica zeolite mutinaite, recently found at Mt. Adamson (Northern Victoria Land, Antarctica). Mutinaite is the natural counterpart of the synthetic zeolite ZSM-5. The new mineral, (Na2.76K0.11Mg0.21Ca3.78) (Al11.20Si84.91) · 6O H2O H2O, is orthorhombic, space group Pnma, with a = 20.201(2), b = 19.991(2), and c = 13.469(2) Å. A single-crystal X-ray diffraction experiment was performed at the synchrotron radiation source ESRF (Grenoble). No Si-Al order in the framework has been detected. Large distances between ions in the channels and framework oxygens suggest weak interactions between the framework and extraframework species.
我们描述了最近在Adamson山(南极洲北维多利亚地)发现的高硅沸石mutinaite的晶体结构。Mutinaite是合成沸石ZSM-5的天然对应物。新矿物(Na2.76K0.11Mg0.21Ca3.78) (Al11.20Si84.91)·60 H2O H2O为正交晶系,空间群为Pnma, a = 20.201(2), b = 19.991(2), c = 13.469(2) Å。在同步辐射源ESRF(格勒诺布尔)上进行了单晶x射线衍射实验。在框架中没有检测到Si-Al的顺序。通道中的离子与框架氧之间的距离较大,表明框架和框架外物种之间的相互作用较弱。