Recent Advances on Tin Oxide Electron Transport Layer for High-Performance Perovskite Solar Cells

Gwang-Hee Lee, Jin‐Wook Lee
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Abstract

In recent years, perovskite solar cells (PSCs) have been considered as a game changer for next-generation photovoltaic industry. A surge of attention originates from unprecedentedly rapid enhancement in power conversion efficiency (PCE) to reach over 25%, being competitive with commercialized silicon solar cells. The charge transporting layer, in particular, an electron transport layer (ETL) is one of the key components for high-performance PSCs. The ETL affords efficient extraction of the photo-generated electrons from the perovskite layer, which are subsequently transferred to transparent conduct oxide electrode. Tin oxide (SnO2) is one of the most attractive materials for the ETL due to its wide band gap, high optical transmission, high carrier mobility and high chemical stability. Moreover, the facile low temperature deposition process of SnO2 layer is suitable for mass production as well as versatile applications such as flexible devices. Regardless of excellent intrinsic properties, however, quality of the functional layer and resulting device performance is largely affected by the fabrication process of the material. In this study, we review the studies to utilize the SnO2 ETL for PSCs by adopting various fabrication processes, ultimately to improve efficiency and stability of the PSCs.
高性能钙钛矿太阳能电池氧化锡电子传输层研究进展
近年来,钙钛矿太阳能电池(PSCs)被认为是下一代光伏产业的游戏规则改变者。由于功率转换效率(PCE)达到了前所未有的25%以上,与商业化的硅太阳能电池竞争,引起了人们的极大关注。电荷传输层,特别是电子传输层(ETL)是高性能psc的关键部件之一。ETL可以有效地从钙钛矿层中提取光产生的电子,这些电子随后转移到透明导电氧化物电极上。氧化锡(SnO2)具有宽带隙、高光透射率、高载流子迁移率和高化学稳定性等优点,是最具吸引力的ETL材料之一。此外,SnO2层易于低温沉积工艺适合批量生产以及柔性器件等多种应用。尽管具有优异的内在性能,但功能层的质量和器件性能在很大程度上受到材料制造工艺的影响。在本研究中,我们回顾了利用SnO2 ETL制备PSCs的研究,并采用了不同的制备工艺,最终提高了PSCs的效率和稳定性。
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