{"title":"Terpane Characterization of Crude Oils from Niger Delta, Nigeria: A Geochemical Appraisal","authors":"Mark Obinna Onyema, Michael Junior Ajie","doi":"10.11648/j.pse.20230701.11","DOIUrl":null,"url":null,"abstract":": The geochemistry of crude oils from the Niger Delta, Nigeria, were evaluated using the characterization of C 19 to C 35 terpanes. Analyses of two representative crude oils from Western and Central Niger Delta showed abundances of C 19 to C 29 tricyclic terpanes constituted 12.09% and 29.74%, C 24 tetracyclic terpane 0.31% and 0.15% and C 27 to C 35 pentacyclic terpanes 87.61% and 70.12%, respectively. Diagnostic ratios of terpanes indicated relatively low abundances of C 23 , C 28 and C 29 tricyclic terpanes, low abundances of homohopanes, a significantly high abundance of oleanane and that the Niger Delta crude oils were derived from terrestrial organic matter source rocks deposited in an oxic environment during the Tertiary period. Multivariate oil-oil correlation plot showed the Western and Central Niger Delta crude oils are not distinct, but moderately related (genetically). However, diagnostic ratios of C 24 tetracyclic terpane, which was high and moderate and gammacerane, which was low and high, revealed crude oils from Western Niger Delta were derived from predominantly terrestrial source and crude oils from Central Niger Delta were derived from terrestrial source with input from marine organic matter, respectively. Tricyclic terpanes/hopanes and isomerization ratios of C 32 homohopanes indicated the Niger Delta crude oils were generated at high maturity, at top of the oil generation window.","PeriodicalId":16717,"journal":{"name":"Journal of Petroleum Science and Engineering","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2023-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Petroleum Science and Engineering","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.11648/j.pse.20230701.11","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"Earth and Planetary Sciences","Score":null,"Total":0}
引用次数: 0
Abstract
: The geochemistry of crude oils from the Niger Delta, Nigeria, were evaluated using the characterization of C 19 to C 35 terpanes. Analyses of two representative crude oils from Western and Central Niger Delta showed abundances of C 19 to C 29 tricyclic terpanes constituted 12.09% and 29.74%, C 24 tetracyclic terpane 0.31% and 0.15% and C 27 to C 35 pentacyclic terpanes 87.61% and 70.12%, respectively. Diagnostic ratios of terpanes indicated relatively low abundances of C 23 , C 28 and C 29 tricyclic terpanes, low abundances of homohopanes, a significantly high abundance of oleanane and that the Niger Delta crude oils were derived from terrestrial organic matter source rocks deposited in an oxic environment during the Tertiary period. Multivariate oil-oil correlation plot showed the Western and Central Niger Delta crude oils are not distinct, but moderately related (genetically). However, diagnostic ratios of C 24 tetracyclic terpane, which was high and moderate and gammacerane, which was low and high, revealed crude oils from Western Niger Delta were derived from predominantly terrestrial source and crude oils from Central Niger Delta were derived from terrestrial source with input from marine organic matter, respectively. Tricyclic terpanes/hopanes and isomerization ratios of C 32 homohopanes indicated the Niger Delta crude oils were generated at high maturity, at top of the oil generation window.
期刊介绍:
The objective of the Journal of Petroleum Science and Engineering is to bridge the gap between the engineering, the geology and the science of petroleum and natural gas by publishing explicitly written articles intelligible to scientists and engineers working in any field of petroleum engineering, natural gas engineering and petroleum (natural gas) geology. An attempt is made in all issues to balance the subject matter and to appeal to a broad readership.
The Journal of Petroleum Science and Engineering covers the fields of petroleum (and natural gas) exploration, production and flow in its broadest possible sense. Topics include: origin and accumulation of petroleum and natural gas; petroleum geochemistry; reservoir engineering; reservoir simulation; rock mechanics; petrophysics; pore-level phenomena; well logging, testing and evaluation; mathematical modelling; enhanced oil and gas recovery; petroleum geology; compaction/diagenesis; petroleum economics; drilling and drilling fluids; thermodynamics and phase behavior; fluid mechanics; multi-phase flow in porous media; production engineering; formation evaluation; exploration methods; CO2 Sequestration in geological formations/sub-surface; management and development of unconventional resources such as heavy oil and bitumen, tight oil and liquid rich shales.