Z.M. Stadnik , J.F. Van Acker, J.C. Fuggle, H.J.W.M. Hoekstra, K.H.J. Buschow, T. Miyazaki, G. Stroink
{"title":"On many-electron effects and multiplet splittings in X-ray photoelectron spectroscopy as a diagnostic tool for metallic glasses","authors":"Z.M. Stadnik , J.F. Van Acker, J.C. Fuggle, H.J.W.M. Hoekstra, K.H.J. Buschow, T. Miyazaki, G. Stroink","doi":"10.1016/0025-5416(88)90335-7","DOIUrl":null,"url":null,"abstract":"<div><p>(Ni<sub>1−x</sub>Fe<sub>x</sub>)<sub>77</sub>Si<sub>10</sub>B<sub>13</sub> glasses and crystalline iron, nickel, Fe<sub>2</sub>Gd and Fe<sub>2</sub>Ti were studied with X-ray photoelectron spectroscopy. It is shown that characteristics of <span><math><mtext>Ni 2p</mtext><msub><mi></mi><mn><mtext>3</mtext><mtext>2</mtext></mn></msub></math></span> satellites are sensitive to changes in the glass composition. It is found that the Fe 3s multiplet splitting, both in glasses and crystalline alloys, does not scale with the iron magnetic moment.</p></div>","PeriodicalId":100890,"journal":{"name":"Materials Science and Engineering","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1988-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0025-5416(88)90335-7","citationCount":"1","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Science and Engineering","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0025541688903357","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 1
Abstract
(Ni1−xFex)77Si10B13 glasses and crystalline iron, nickel, Fe2Gd and Fe2Ti were studied with X-ray photoelectron spectroscopy. It is shown that characteristics of satellites are sensitive to changes in the glass composition. It is found that the Fe 3s multiplet splitting, both in glasses and crystalline alloys, does not scale with the iron magnetic moment.
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