Recyclable magnetic nanocomposites for efficient removal of cadmium ions from water: performance, mechanism and isotherm studies

IF 3.6 4区环境科学与生态学 Q2 BIOCHEMISTRY & MOLECULAR BIOLOGY

Environmental Pollutants and Bioavailability Pub Date : 2023-01-04 DOI:10.1080/26395940.2022.2163922

Saad Melhi

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引用次数: 2

Abstract

ABSTRACT Herein, succinic acid functionalized Fe3O4@AMPA nanocomposite was synthesized as an effective adsorbent and used for the efficient removal of Cd(II) ions from aqueous media. Zeta potential, BET, TEM, TGA, and FTIR spectra were applied to characterize the Fe3O4@AMPA@SA nanocomposite. According to the BET analysis, the surface area of Fe3O4@AMPA@SA was found to be 43 m2/g. The influence of pH value, initial Cd(II) concentration, adsorbent dosage, temperature, and contact time on the adsorption process was achieved via the batch experiment method. The result showed that the optimal parameters were 6, 250 mg/L, 0.03 g/50 mL, 150 min, and 25°C, respectively. The experimental data fitted well to the Langmuir isotherm and the pseudo-first-order models. The maximum monolayer adsorption capacity of Cd(II) ions was 265 mg g−1. The adsorption mechanism of Cd(II) on magnetic nanocomposite is physical adsorption. The Fe3O4@AMPA@SA nanocomposite shows excellent reusability with a removal efficiency of 81.4% after three cycles. GRAPHICAL ABSTRACT

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来源期刊

Environmental Pollutants and Bioavailability Chemical Engineering-Chemical Health and Safety

CiteScore

4.30

自引率

3.00%

发文量

审稿时长

13 weeks

期刊介绍： Environmental Pollutants & Bioavailability is a peer-reviewed open access forum for insights on the chemical aspects of pollutants in the environment and biota, and their impacts on the uptake of the substances by living organisms. Topics include the occurrence, distribution, transport, transformation, transfer, fate, and effects of environmental pollutants, as well as their impact on living organisms. Substances of interests include heavy metals, persistent organic pollutants, and emerging contaminants, such as engineered nanomaterials, as well as pharmaceuticals and personal-care products as pollutants.